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Cooperative Bimetallic Reactivity of a Heterodinuclear Molybdenum-Copper Model of Mo-Cu CODH

The synthesis of a heterodinucleating ligand LH2 (LH2 = (E)-3-(((2,7-di-tert-butyl-9,9-dimethyl-5-((pyridin-2-ylmethylene)amino)-9H-xanthen-4-yl)amino)methyl)benzene-1,2-diol) was undertaken toward a functional model of the bimetallic active site found in Mo-Cu carbon monoxide dehydrogenase (Mo-Cu CODH), and

Authors:   Stanislav Groysman; Thilini Hollingsworth; Ryan L Hollingsworth; Richard L Lord
Journal:   Dalton Transactions
DOI:   10.1039/C8DT02323A
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