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Enabling multi-electron reaction of ε-VOPO4 to reach theoretical capacity for lithium-ion batteries

By controlling the morphology and particle size of the epsilon polymorph of vanadyl phosphate, ε-VOPO4, it can fully reversibly intercalate two Li-ions and reach the theoretical capacity of 305 mA h g−1 over two voltage plateaus at about 4.0 and 2.5 V.

Authors:   Carrie Siu; Ieuan D. Seymour; Sylvia Britto; Hanlei Zhang; Jatinkumar Rana; Jun Feng; Fredrick O. Omenya; Hui Zhou; Natasha A. Chernova; Guangwen Zhou; Clare P. Grey; Louis F. J. Piper; M. Stanley Whittingham
Journal:   Chemical Communication
DOI:   10.1039/C8CC02386G
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