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Palladium catalyzed stereocontrolled synthesis of C-aryl glycosides using glycals and arenediazonium salts at room temperature

A stereocontrolled synthesis of aryl-C-glycosides was achieved using glycals and aryldiazonium salts in the presence of palladium acetate. A wide range of glycals including D-glucal, D-galactal, L-rhamanal, D-xylal and D-ribal underwent C-arylation at the anomeric carbon in the presence of different aryldiaz Synthetic methodology in OBC

Authors:   Jeyakumar Kandasamy; Adesh Kumar Singh
Journal:   Organic & Biomolecular Chemistry
DOI:   10.1039/C8OB01393D
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  • Arylation
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