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Highly strained [6]cycloparaphenylene: crystallization of an unsolvated polymorph and the first mono- and dianions

An X-ray diffraction study of [6]cycloparaphenylene (1), crystallized under solvent-free conditions, revealed a unique solid state structure with tight packing of individual molecules that minimizes empty internal space. The controlled chemical reduction of this highly strained nanohoop with Group 1 metals resulted

Authors:   Sarah N. Spisak; Zheng Wei; Evan Darzi; Ramesh Jasti; Marina A. Petrukhina
Journal:   Chemical Communication
DOI:   10.1039/C8CC03693D
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