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Carbenium ion formation by fragmentation of electrochemically generated oxonium ions

Fragmentation of electrochemically generated oxonium ions can be exploited to form carbenium ions at low oxidation potential in the presence of a nuclephile. The application of this concept is demonstrated for allylation of carbenium ions generated by anodic oxidation of stannylmethylethers. Synthetic methodology in OBC

Authors:   Anna Lielpetere; Aigars Jirgensons
Journal:   Organic & Biomolecular Chemistry
DOI:   10.1039/C8OB01339J
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