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Cu(II)–tBu–PHOX catalyzed enantioselective malonate addition onto 3-hydroxy 2-oxindoles: application in the synthesis of dimeric pyrroloindoline alkaloids

An efficient Cu(ii)–PHOX-catalyzed malonate addition onto 3-hydroxy 3-indolyl-2-oxindoles is envisioned to afford excellent enantioselectivities (up to >99% ee) in high chemical yields. Detailed characterization techniques including X-ray, NMR, CV and EPR experiments suggest that a Cu(ii)-complex is involved as an

Authors:   K. Naresh Babu; Lakshmana K. Kinthada; Partha Pratim Das; Alakesh Bisai
Journal:   Chemical Communication
DOI:   10.1039/C8CC04338H
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