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Simple Generation of a Dirhodium [small mu ]-Carbido Complex via Thiocarbonyl Reduction

The reaction of [RhCl(CS)(PPh3)2] with excess catecholborane affords the cumulenic carbido complex [Rh2(μ-C)Cl2(PPh3)4] which undergoes phosphine and halide substitution to afford a range of complexes in which the Rh=C=Rh spine remains intact. Amongst these, the reactions with K[L] (L = H2B(pz)2, H2B(pzMe2)2

Authors:   Anthony Hill; Harrison J Barnett; Liam K Burt
Journal:   Dalton Transactions
DOI:   10.1039/C8DT02524J
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