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Redox-induced switch between luminescent and magnetic properties in a trinuclear cyanide-bridged compound

A trinuclear cyanide-bridged luminescent compound trans-RuII(DMAP)4(CN)2[(PY5Me2)Mn]2[PF6]4 (1-R) and its oxidation product, ferromagnetic trans-RuIII(DMAP)4(CN)2[(PY5Me2)Mn]2-[PF6]5 (1-O) have been synthesized and fully characterized. This is the first example of molecular materials about redox-controlled t

Authors:   Xiao-quan Zhu; Shaodong Su; Yuehong Wen; Lintao Zhang; Yu-YIing Yang; Xintao Wu; Tianlu Sheng
Journal:   Dalton Transactions
DOI:   10.1039/C8DT01905C
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