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Electrochemical properties and C-H bond oxidation activity of [Ru(tpy)(pyalk)Cl]+ and [Ru(tpy)(pyalk)(OH)]+

[Ru(tpy)(pyalk)Cl]Cl (pyalk = 2-(2’-Pyridyl)-2-propanol) was synthesized and characterized crystallographically and electrochemically. Upon dissolution in water and acetonitrile, [Ru(tpy)(pyalk)Cl]Cl was found to form [Ru(tpy)(pyalk)Cl]+ and [Ru(tpy)(pyalk)(OH)]+, respectively. The Ru(II/III) couple of [Ru(t

Authors:   Christian K Nilles; Hashini Herath; Hanna Fanous; Angel Ugrinov; Alexander Rene Parent
Journal:   Dalton Transactions
DOI:   10.1039/C8DT02260G
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