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Direct Metal-free, Base Catalysed sp2 C-H Functionalization in Sulfonamidation of 1,4-Naphthoquinones Using Sulfonyl azides

A novel metal-free, base catalysed sp2 C-H functionalization in the sulfonyl amidation of 1,4-naphthoquinones via a [3+2] cycloaddition reaction using sulfonyl azides under mild reaction conditions is reported. In this straightforward, atom- and step-economical protocol, the active alkene moiety of quinone u Synthetic methodology in OBC

Authors:   Pitchumani Kasi; Ramanathan Devenderan
Journal:   Organic & Biomolecular Chemistry
DOI:   10.1039/C8OB00818C
Facts, background information, dossiers
  • Cycloaddition
  • Amidation
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