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Synthesis and structure of arylselenium(II) and aryltellurium(II) cations based on rigid 5-tert-butyl-1,3-bis-(N-pentylbenzimidazol-2[prime or minute]-yl)benzenes

The transmetalation reactions of a mercury precursor, [Pentyl(N^C^N)HgCl] (19), with selenium halides (SeCl4, SeBr4, and SeCl2) were attempted to obtain the corresponding organoselenium trichloride [Pentyl(N^C^N)SeCl3], tribromide [Pentyl(N^C^N)SeBr3], and monochloride [Pentyl(N^C^N)SeCl], respectively [(N^C^N) = 5

Authors:   Varsha Rani; Manjusha Boda; Saravanan Raju; G. Naresh Patwari; Harkesh B. Singh; Ray J. Butcher
Journal:   Dalton Transactions
DOI:   10.1039/C8DT01148F
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