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On the possibility of an Eley–Rideal mechanism for ammonia synthesis on Mn6N5+x (x = 1)-(111) surfaces

Recently we reported an Eley–Rideal/Mars–van Krevelen mechanism for ammonia synthesis on cobalt molybdenum nitride (Co3Mo3N). In this mechanism hydrogenation of activated dinitrogen occurs directly from the gas phase in a low barrier step forming a hydrazinylidene intermediate [[double bond, length as m-dash]]...

Authors:   Constantinos D. Zeinalipour-Yazdi
Journal:   Physical Chemistry Chemical Physics
DOI:   10.1039/C8CP02381F
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  • ammonia synthesis
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