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Effects of diminished steric protection at phosphorus on stability and reactivity of oxaphosphirane complexes

Readily available P-tBu substituted Li/Cl phosphinidenoid complexes react with carbonyl compounds to furnish sterically almost unhindered oxaphosphirane complexes that reveal new and surprisingly facile intra- and intermolecular ring expansion reactions. 1,3,2-Dioxaphosphole complex formation is explained by DFT ca

Authors:   J. Fassbender; G. Schnakenburg; A. Espinosa Ferao; R. Streubel
Journal:   Dalton Transactions
DOI:   10.1039/C8DT01979G
Facts, background information, dossiers
  • complexes
  • stability
  • Ring Expansion
  • carbonyl compounds
More about RSC Publishing
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