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A bifunctional cationic metal–organic framework based on unprecedented nonanuclear copper(II) cluster for high dichromate and chromate trapping and highly efficient photocatalytic degradation of organic dyes under visible light irradiation

A bifunctional cationic metal–organic framework {[Cu9(OH)6Cl2(itp)6(1,4-bdc)3](NO3)2(OH)2·20H2O}n (1-NO3-OH·20H2O) was synthesized and characterized (itp = 1-imidazol-1-yl-3-(1,2,4-triazol-4-yl)propane, 1,4-bdc = 1,4-benzenedicarboxylate). In 1-NO3-OH·20H2O, three [Cu3(μ3-OH)(μ2-OH)] trimeric clusters are bridged b

Authors:   Tian-Rui Zheng; Lin-Lu Qian; Min Li; Zhi-Xiang Wang; Ke Li; Ya-Qian Zhang; Bao-Long Li; Bing Wu
Journal:   Dalton Transactions
DOI:   10.1039/C8DT01685B
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