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Asymmetric Organocatalytic Synthesis of Chiral 3,3-Disubstituted Oxindoles via 1,6-Conjugate Addition Reaction

A highly efficient synthesis of chiral 3,3-disubstituted oxindoles was developed by using a chiral spirocyclic phosphoric acid catalyzed 1,6-conjugate addition reaction of para-quinone methoids derived from N-unprotected isatins with indoles. The reaction proceeds under mild reaction conditions to provide in Synthetic methodology in OBC

Authors:   Abdul Rahman; Qiaoxia Zhou; Xufeng Lin
Journal:   Organic & Biomolecular Chemistry
DOI:   10.1039/C8OB01169A
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