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Drastic rearrangement of self-assembled hydrogen-bonded tapes in a molecular crystal

A 2 : 1 hydrogen-bonded crystal of 2-pyrrolidone and chloranilic acid shows structural phase transitions accompanied by the drastic rearrangement of hydrogen-bonded tapes. Such a phenomenon is attributed to the selective and directional character of hydrogen bonds.

Authors:   Masaki Donoshita; Mikihiro Hayashi; Ryuichi Ikeda; Yukihiro Yoshida; Shota Morikawa; Kunihisa Sugimoto; Hiroshi Kitagawa
Journal:   Chemical Communication
DOI:   10.1039/C8CC04376K
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  • hydrogen bonds
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