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Preparation and reactivity of half-sandwich dioxygen complexes of ruthenium

Dioxygen complexes [Ru(η5-C5Me5)(η2-O2){P(OEt)3}2]BPh4 (1) and [Ru(η5-C5Me5)(η2-O2)(PPh3){P(OR)3}]BPh4 (2, 3) [R = Me (2), Et (3)] were prepared by allowing chloro-complexes RuCl(η5-C5Me5)[P(OEt)3]2 and RuCl(η5-C5Me5)(PPh3)[P(OR)3] to react with air (1 atm) in the presence of NaBPh4. Substitution of the η2-O2 in 1–

Authors:   Gabriele Albertin; Stefano Antoniutti; Marco Bortoluzzi; Jesús Castro; Valentina Ferraro
Journal:   Dalton Transactions
DOI:   10.1039/C8DT01871E
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