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Continuum of Covalent to Intermolecular Bonding in the Halogen-Bonded Complexes of 1,4-Diazabicyclo[2.2.2]octane with Bromine-Containing Electrophiles

A gradual change of Br···N bond lengths and strengths from the values typical for intermolecular associates to that characteristic of a covalent bond was observed in the series of the halogen-bonded complexes. This continuum reveals fundamental relationship between the limiting types of bonding and implies t

Authors:   Craig Weinberger; Rachel Hines; Matthias Zeller; Sergiy Rosokha
Journal:   Chemical Communication
DOI:   10.1039/C8CC04629H
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