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Arene-Tethered Silylene Ligand Enabling Reversible Dinitrogen Binding to Iron and Catalytic Silylation

The arene-tetherd silylene ligand L (L = PhC(tBuN)2SiCH2C(tBu)NAr, Ar = 2,6-iPr2C6H3) allowed the synthesis of the three-coordinate Fe(II) silylamido and piano-stool Fe(0) dinitrogen complexes LFe[N(SiMe3)2]2 (3) and LFe-N2 (4), which not only exhibit interesting bonding but also enabled catalytic silyaltion

Authors:   Yunping Bai; Jianying Zhang; Chunming Cui
Journal:   Chemical Communication
DOI:   10.1039/C8CC03734E
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