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Redox-enhanced hemilability of the tris(tert-butoxy)siloxy ligand at cerium

The stabilizing effect of the tris(tert-butoxy)silyoxy ligand on cerium(IV) is revealed by electrochemical and computation methods as well as targeted redox chemistry. Ceric homoleptic complex Ce[OSi(OtBu)3]4 was obtained by the reaction of [Et4N]2[CeCl6] with NaOSi(OtBu)3 at ambient temperature in acetonitr

Authors:   Jochen Friedrich; Yusen Qiao; Caecilia Maichle-moessmer; Eric J Schelter; Reiner Anwander
Journal:   Dalton Transactions
DOI:   10.1039/C8DT01878B
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