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Direct water-based synthesis and characterization of new Zr/Hf-MOFs with dodecanuclear clusters as IBU

Two new metal-organic framework compounds of composition [M12(μ3-O)8(μ3-OH)8(μ-OH)6(OH)6(H2O)6(APDC)6], with M = Zr and Hf denoted as M-CAU-39, containing the azopyridinedicarboxylate ion (APDC2-) as a new linker, were obtained by a water based synthesis. The crystal structure was determined from powder X-ra

Authors:   Steve Waitschat; Helge Reinsch; Merve Arpacioglu; Norbert Stock
Journal:   CrystEngComm
DOI:   10.1039/C8CE00949J
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