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Preparation of polynuclear NHC complexes by post-synthetic modification of half-sandwich rhodium and iridium complexes bearing C-azolato ligands

A series of bimetallic and trimetallic complexes has been prepared by N-alkylation of mononuclear half-sandwich rhodium and iridium di-NHC complexes featuring bidentate chelate ligands composed of a classical NHC and a C-azolato donor. The shape and the separation between metal centers in the obtained complexes are

Authors:   Francisco Aznarez; Wen-Xi Gao; Yue-Jian Lin; F. Ekkehardt Hahn; Guo-Xin Jin
Journal:   Dalton Transactions
DOI:   10.1039/C8DT02212G
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