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Cyclometalated Ir(III) complexes [Ir(tpy)(bbibH2)Cl][PF6] and [Ir(tpy)(bmbib)Cl][PF6]: intramolecular ∙∙∙ interaction leading to facile synthesis and enhanced luminescence

Cyclometalated Ir(III) complexes [Ir(tpy)(bbibH2)Cl][PF6] (1PF6) and [Ir(tpy)(bmbib)Cl][PF6] (2PF6), and the controlled complex [Ir(tpy)(mbib)Cl][PF6] (3PF6) have been synthesized at 135 oC for 10 hours for the former two complexes, while at 190 oC for 24 hours for the latter complex (Scheme 1), in which

Authors:   Zhong-Ze Qu; Tao-Bao Gao; Jing Wen; Kai Rui; Haibo Ma; Deng-Ke Cao
Journal:   Dalton Transactions
DOI:   10.1039/C8DT01922C
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