Chemical sensing with 2D materials

Atomic hydrogen interactions with gas-phase coronene cations: hydrogenation versus fragmentation

Sequential hydrogenation of polycyclic aromatic hydrocarbon (PAH) cations drives a gradual transition from a planar to a puckered geometry and from an aromatic to an aliphatic electronic structure. The resulting H-induced weakening of the molecular structure together with the exothermic nat ... more

Silver(I)-catalyzed sequential hydroamination and Prins type cyclization for the synthesis of fused benzo--sultams

An intramolecular annulation strategy has been developed for the synthesis of tetrahydrobenzo[e]pyrano[4,3-c][1,2]thiazine derivatives by means of coupling of aldehydes with 2-(4-hydroxybut-1-yn-1-yl)-N-arylsulfonamides using a catalytic amount of silver hexafluoroantimonate in toluene at 8 ... more

Effect of copolymer sequence on structure and relaxation times near a nanoparticle surface

We simulate a simple nanocomposite consisting of a single spherical nanoparticle surrounded by coarse-grained polymer chains. The polymers are composed of two different monomer types that differ only in their interaction strengths with the nanoparticle. We examine the effect of adjusting co ... more

‘Forensic fingers’ for crime scene investigation

A team of scientists in the United States has developed a wearable fingertip sensor to enable crime scene investigators to rapidly detect explosives and gunshot residue. Traditional forensic analysis is typically carried out in a central laboratory, which requires time-consuming processes s ... more

High-performance epoxy resin adhesives from renewable green starting materials

A series of epoxy resins has been synthesised by a team of chemists from Germany, who used renewable starting materials for a more environmentally friendly approach than conventional methods. The resulting epoxy resins have highly desirable mechanical properties, such as high stiffness, tha ... more

Electrospun polymer fibres better than non-woven polymer fibres at mopping up oil from oil spills

Electrospun polystyrene shell/polyurethane core fibres made by scientists in China have absorption capacities 2-3 times higher than reported for non-woven polypropylene fibres (widely used to clean up oil spills). Electrospun fibres are an ideal candidate for soaking up oil, as their struct ... more