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Fluoro-containing 4-ethylidene-2,4-dihydropyrazol-3-ones in the Diels-Alder reaction with cyclopentadiene and cyanamines

The fluorinated 4-ethylidene-2,4-dihydropyrazol-3-ones act as heterodienes and dienophiles in the Diels-Alder reaction with amines and cyclopentadiene to give 1,4-dihydropyrazolo[4,3-e]-1,3-oxazines and spirobicyclo[2.2.1]hept-5-ene-2,4′-pyrazolones, respectively.

Authors:   V. B. Sokolov, A. Yu. Aksinenko, T. A. Epishina, T. V. Goreva
Journal:   Russian Journal of General Chemistry
Volume:   82
edition:   10
Year:   2012
Pages:   1728
DOI:   10.1134/S1070363212100155
Publication date:   19-Nov-2012
Facts, background information, dossiers
  • Diels-Alder Reaction
  • cyclopentadiene
  • amines
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