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An Exceptionally High Boron Content Supramolecular Cuboctahedron

A boron-rich supramolecular cuboctahedron containing an impressive 240 boron atoms has been synthesized via coordination-driven assembly. The cuboctahedron, which is composed of Cu2+ paddle-wheel nodes and carborane–isophthalic acids, was obtained simply and in high purity. The ability to precisely character

Authors:   Daniel J Clingerman; Robert Daniel Kennedy; Joseph E Mondloch; Amy Sarjeant; J T Hupp; Omar Farha; Chad A Mirkin
Journal:   Chemical Communication
DOI:   10.1039/C3CC44173C
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