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Solid State Structural Transformation of 1D to Intermediate 2D and then to 3D Porous Coordination Polymer by Anion Replacement; New Precursors for Preparation of PbCl2, Pb3O2Cl2 and PbO Nanoparticles

A reversible anion-exchange of 1D lead(II) coordination polymers with the ligand 2,5-bis(4-pyridyl)-3,4-diaza-2,4-hexadiene (4-bpdh), from [Pb(4-bpdh)Cl2]n (1) to intermediate 2D [Pb(4-bpdh)(Cl)(NO3)]n (2) and then 3D porous coordination polymer [Pb(4-bpdh)(NO3)2(H2O)]n (3) by solid state anion-replacement p

Authors:   Ali Morsali; Lida Hashemi
Journal:   CrystEngComm
DOI:   10.1039/C3CE41566J
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