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C2N14 – ein energetisches und höchst empfindliches binäres Azidotetrazol

7:1 für Stickstoff! Diazotierung und anschließende Dimerisierung des Triaminoguanidinium‐Kations führen zur Titelverbindung 1‐Diazido‐carbamoyl‐5‐azidotetrazol. Die strukturell und spektroskopisch komplett charakterisierte binäre CN‐Verbindung zeigt hervorragende energetische Eigenschaften und verfügt über eine sehr hohe Standardbildungsenthalpie, was jedoch auch zu einer extremen Empfindlichkeit gegen Stoß und Reibung führt.

Authors:   Klapötke, Thomas M.; Martin, Franz A.; Stierstorfer, Jörg
Journal:   Angewandte Chemie
Volume:   123
edition:   18
Year:   2011
Pages:   4313
DOI:   10.1002/ange.201100300
Publication date:   26-Apr-2011
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