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Design of recombinant whole-cell catalysts for double reduction of C[double bond, length as m-dash]C and C[double bond, length as m-dash]O bonds in enals and application in the synthesis of Guerbet alcohols as industrial bulk chemicals for lubricants

Whole-cell catalysts overexpressing two enzymes for a double reduction cascade in which aliphatic α-branched α,β-unsaturated aldehydes are converted into Guerbet alcohols as a highly demanded class of lubricants were constructed and characterized. The reaction conditions were optimized to suppress by-product format

Authors:   Marc Biermann; Daniel Bakonyi; Werner Hummel; Harald Gröger
Journal:   Green Chemistry
DOI:   10.1039/C6GC01668E
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