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2,257 Newest Publications in inorganic chemistry communications

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Synthesis of new red photoluminescent Zn(II)-Salicylaldiminato complex

18-Mar-2010 | Vincenzo, Liuzzo , Werner, Oberhauser , Andrea, Pucci, Inorganic Chemistry Communications, 2010

We report the preparation and photophysical properties of a new zinc (II) complex of the donor–acceptor–donor (D–A–D) type ligand N,N’-bis(2-hydroxy-1- naphthylidene)-diaminomaleonitrile (H2L). The molecular structure of the [(ZnL).DMF].DMF complex was determined by single crystal X-ray ...

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On the reaction mechanism of MoS42− with nitric oxide

17-Mar-2010 | Inna, Popivker , Israel, Zilbermann , Eric, Maimon , Dror, Shamir , Naomi, Meyerstein , ..., Inorganic Chemistry Communications, 2010

MoS42− (TTM) reacts in deaerated neutral phosphate buffered aqueous solutions with NO. Three consecutive reactions are observed. The two first ones obey pseudo first order rate laws with observed rates proportional to [NO]. The third reaction obeys a first order rate law. Nitrite is one of the ...

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Complexation and structural studies of a sulfonamide aza-15-crown-5 derivative

17-Mar-2010 | Marie, Ioannidis , Alexander S., Gentleman , Lam, Ho , Stephen F., Lincoln , Christopher J., Sumby, Inorganic Chemistry Communications, 2010

An aza-15-crown-5 derivative, N-[4-(phenyldiazo)benzenesulfonyl]-aza-15-crown-5, 1 was synthesised from commercially available starting materials in 55% yield. Compound 1, which contains a sulfonamide link between the crown ether macroring and the azobenzene, readily binds alkali metals in ...

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Cation-cation interaction in novel Np(V) compound with methylimidazole as a model of histidine side chain

17-Mar-2010 | Grigory, Andreev , Nina, Budantseva , Ivan, Tananaev , Boris, Myasoedov, Inorganic Chemistry Communications, 2010

The reaction of NpO2(CH3SO3) with methylimidazole results in the formation of novel Np(V) complex with cation-cation interaction, [NpO2(MeIm)(CH3SO3)(H2O)]. The crystal structure is confirmed by IR and UV-vis spectroscopic data.

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Lanthanide complexes with 8-quinolinyloxyacetate (qoa): Synthesis and supramolecular assembly by hydrogen bonds

16-Mar-2010 | Jun, Fan , Zhi-Hong, Wang , Zhuo-Fen, Huang , Xia, Yin , Wei-Guang, Zhang, Inorganic Chemistry Communications, 2010

Two new lanthanide supramolecular complexes, [Tb(qoa)2(H2O)2]·NO3·H2O (1) and [Er(qoa)3]·2H2O (2) [qoa=(8-quinolinyloxy)acetate] were obtained by treating the corresponding nitrates and (8-quinolinyloxy)acetic acid (Hqoa) under hydrothermal conditions. Complex 1 possesses a 1D zigzag chain ...

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Improving the relaxivity by dimerizing Gd-AAZTA: Insights for enhancing the sensitivity of MRI contrast agents

16-Mar-2010 | Eliana, Gianolio , Kondareddiar, Ramalingam , Bo, Song , Ferenc, Kalman , Silvio, Aime , ..., Inorganic Chemistry Communications, 2010

The synthesis of a dimeric derivative of Gd-AAZTA is reported. It retains the basic properties of the parent complex (q=2, high stability) and displays a relaxivity of 14.0mM-1s-1 at 20MHz and 298K. The outstanding relaxivity is the result of the increased molecular reorientational time and of ...

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A highly rare (3,4,5,6)-connected metal-organic framework containing three distinct Co2 secondary building units

16-Mar-2010 | Feng, Luo , Yang, Ning , Xiao-lan, Tong , Ming-biao, Luo, Inorganic Chemistry Communications, 2010

Via solvothermal reaction of CoCl2 with H3BTC (1,3,5-benzenetricarboxylic acid) in DMF-C2H5OH, a new metal-organic framework (MOF) was isolated. The single crystal X-ray diffraction suggests that the asymmetric unit contains six crystallography-independent Co(II) ions and four deprotonated BTC3- ...

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