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10,093 Newest Publications in inorganic chemistry

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Modulating the Magnetic Interaction in New Triple-Decker Dysprosium(III) Single-Molecule Magnets

09-Jan-2018 | Jing-Yuan Ge; Hai-Ying Wang; Jian Su; Jing Li; Bao-Lin Wang; Yi-Quan Zhang; Jing-Lin Zuo, Inorganic Chemistry, 2018

A new type of dinuclear dysprosium(III) complex based on phthalocyanine and salicylaldehyde derivatives (HL-R), [Dy2(Pc)2(L-R)2(H2O)]·2THF (R = OCH3 (1), OC2H5 (2); H2Pc = phthalocyanine; HL-OCH3 = 2-hydroxy-3-methoxybenzaldehyde; HL-OC2H5 = 3-ethoxy-2-hydroxybenzaldehyde), was successfully ...

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Organometallic Zirconium Compounds in an Oxygen-Rich Coordination Environment: Synthesis and Structural Characterization of Tris(oxoimidazolyl)hydroboratozirconium Compounds

09-Jan-2018 | Ahmed Al-Harbi; Matthew J. Hammond; Gerard Parkin, Inorganic Chemistry, 2018

A series of tris(oxoimidazolyl)hydroborato ligands, which serve as L2X [O3] donors, have been employed to obtain organometallic zirconium compounds in an uncommon oxygen-rich coordination environment. For example, Cp[ToMeBenz]ZrCl2 has been synthesized via the reaction of [ToMeBenz]Na with ...

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Contribution of Coulomb Interactions to a Two-Step Crystal Structure Phase Transformation Coupled with a Significant Change in Spin Crossover Behavior for a Series of Charged FeII Complexes from 2,6-Bis(2-methylthiazol-4-yl)pyridine

08-Jan-2018 | Kazuyuki Takahashi; Mitsunobu Okai; Tomoyuki Mochida; Takahiro Sakurai; Hitoshi Ohta; Takashi Yamamoto; Yasuaki Eina ..., Inorganic Chemistry, 2018

A series of [FeII(L)2](BF4)2 compounds were structurally and physically characterized (L = 2,6-bis(2-methylthiazol-4-yl)pyridine). A crystal structure phase transformation from dihydrate compound 1 to anhydrous compound 3 through partially hydrated compounds 2 and 2′ upon dehydration was found. ...

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Contribution of Coulomb Interactions to a Two-Step Crystal Structure Phase Transformation Coupled with a Significant Change in Spin Crossover Behavior for a Series of Charged FeII Complexes from 2,6-Bis(2-methylthiazol-4-yl)pyridine

08-Jan-2018 | Kazuyuki Takahashi; Mitsunobu Okai; Tomoyuki Mochida; Takahiro Sakurai; Hitoshi Ohta; Takashi Yamamoto; Yasuaki Eina ..., Inorganic Chemistry, 2018

A series of [FeII(L)2](BF4)2 compounds were structurally and physically characterized (L = 2,6-bis(2-methylthiazol-4-yl)pyridine). A crystal structure phase transformation from dihydrate compound 1 to anhydrous compound 3 through partially hydrated compounds 2 and 2′ upon dehydration was found. ...

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Palladium Complexes of N,N′-Bis(2-aminoethyl)oxamide (H2L): Structural (PdIIL, PdII2L2, and PdIVLCl2), Electrochemical, Dynamic 1H NMR, and Cytotoxicity Studies

08-Jan-2018 | Sergey P. Gavrish; Yaroslaw D. Lampeka; Maria V. Babak; Vladimir B. Arion, Inorganic Chemistry, 2018

The monomeric (PdL·2H2O) and dimeric (Pd2L2·7H2O) palladium(II) complexes of N,N′-bis(2-aminoethyl)oxamide (H2L) were isolated, and their structures were established by single-crystal X-ray diffraction. Both compounds display identical cis-(2Namide + 2Namine) coordination environments of the ...

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Palladium Complexes of N,N′-Bis(2-aminoethyl)oxamide (H2L): Structural (PdIIL, PdII2L2, and PdIVLCl2), Electrochemical, Dynamic 1H NMR, and Cytotoxicity Studies

08-Jan-2018 | Sergey P. Gavrish; Yaroslaw D. Lampeka; Maria V. Babak; Vladimir B. Arion, Inorganic Chemistry, 2018

The monomeric (PdL·2H2O) and dimeric (Pd2L2·7H2O) palladium(II) complexes of N,N′-bis(2-aminoethyl)oxamide (H2L) were isolated, and their structures were established by single-crystal X-ray diffraction. Both compounds display identical cis-(2Namide + 2Namine) coordination environments of the ...

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Fluorescent Metal–Organic Framework (MOF) as a Highly Sensitive and Quickly Responsive Chemical Sensor for the Detection of Antibiotics in Simulated Wastewater

08-Jan-2018 | Xian-Dong Zhu; Kun Zhang; Yu Wang; Wei-Wei Long; Rong-Jian Sa; Tian-Fu Liu; Jian Lü, Inorganic Chemistry, 2018

A Zn(II)-based fluorescent metal–organic framework (MOF) was synthesized and applied as a highly sensitive and quickly responsive chemical sensor for antibiotic detection in simulated wastewater. The fluorescent chemical sensor, denoted FCS-1, exhibited enhanced fluorescence derived from its ...

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Coumarin Derivative Directly Coordinated to Lanthanides Acts as an Excellent Antenna for UV–Vis and Near-IR Emission

08-Jan-2018 | Óscar Guzmán-Méndez; Federico González; Sylvain Bernès; Marcos Flores-Álamo; Javier Ordóñez-Hernández; Héctor García ..., Inorganic Chemistry, 2018

Inorganic Chemistry DOI: 10.1021/acs.inorgchem.7b02861

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Synthesis, Structure, and Optical Properties of Antiperovskite-Derived Ba2MQ3X (M = As, Sb; Q = S, Se; X = Cl, Br, I) Chalcohalides

08-Jan-2018 | Ruiqi Wang; Xian Zhang; Jianqiao He; Kejun Bu; Chong Zheng; Jianhua Lin; Fuqiang Huang, Inorganic Chemistry, 2018

Six isostructural antiperovskite-derived chalcohalides, Ba2MQ3X (M = As, Sb; Q = S, Se; X = Cl, Br, I), crystallizing in the space group Pnma, have been synthesized by solid-state reactions. The crystal structure features a 3D framework with the [XBa5]9+ disordered square pyramids as building ...

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Comparative Study on Temperature-Dependent CO2 Sorption Behaviors of Two Isostructural N-Oxide-Functionalized 3D Dynamic Microporous MOFs

08-Jan-2018 | Wen-Qian Zhang; Rui-Dong Wang; Zi-Bo Wu; Yi-Fan Kang; Yan-Ping Fan; Xi-Qiang Liang; Ping Liu; Yao-Yu Wang, Inorganic Chemistry, 2018

By functionalization of the achiral carboxylate-based pyridine-N ligand 2,2′-bipyridine-3,3′-dicarboxylate (H2bpda) with N-oxide groups, the axially chiral ligand 2,2′-bipyridine-3,3′-dicarboxylate 1,1′-dioxide (H2bpdado) has been obtained. On the basis of H2bpdado and auxiliary N-donor ligands, ...

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