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17,838 Newest Publications in journal of the american chemical societyrss
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19-Jan-2018 | Zhuang Wu; Ruijuan Feng; Jian Xu; Yan Lu; Bo Lu; Tao Yang; Gernot Frenking; Tarek Trabelsi; Joseph S. Francisco; Xia ..., Journal of the American Chemical Society, 2018
An exotic ternary S, N, O heterocumulene OSNSO in syn-syn (A) and syn-anti (B) conformations has been generated in the gas phase through flash vacuum pyrolysis of CF3S(O)NSO at 700 K. Upon visible light irradiation (570 ± 20 or 532 nm), both A and B, isolated in cryogenic matrices (N2, Ne, Ar, ...
19-Jan-2018 | Peter R. Schreiner, Journal of the American Chemical Society, 2018
Journal of the American Chemical Society DOI: 10.1021/jacs.8b00446
19-Jan-2018 | Young-Hee Shin; Samuel H. Gellman, Journal of the American Chemical Society, 2018
We have evaluated the impact of changes in the chemical structure of peptidic oligomers containing α-, β-, and γ-amino acid residues (α/β/γ-peptides) on the propensities of these oligomers to adopt helical conformations in aqueous and alcoholic solutions. These studies were inspired by our ...
19-Jan-2018 | Moritz Pott; Takahiro Hayashi; Takahiro Mori; Peer R. E. Mittl; Anthony P. Green; Donald Hilvert, Journal of the American Chemical Society, 2018
Expanding the range of genetically encoded metal coordination environments accessible within tunable protein scaffolds presents excellent opportunities for the creation of metalloenzymes with augmented properties and novel activities. Here, we demonstrate that installation of a noncanonical ...
18-Jan-2018 | Michael S. Denny, Jr.; Lucas R. Parent; Joseph P. Patterson; Santosh Kumar Meena; Huy Pham; Patricia Abellan; Quenti ..., Journal of the American Chemical Society, 2018
Postsynthetic strategies for modifying metal–organic frameworks (MOFs) have proven to be an incredibly powerful approach for expanding the scope and functionality of these materials. Previously, we reported on the postsynthetic exchange (PSE) of metal ions and ligands in the University of Oslo ...
18-Jan-2018 | Yao Yao; Shangqian Zhu; Haijiang Wang; Hui Li; Minhua Shao, Journal of the American Chemical Society, 2018
The electrochemical reduction of nitrogen to ammonia on Au-based catalysts showed a reasonably high Coulombic efficiency. The pathway of this promising reaction, however, is not clear partially due to the lack of information on reaction intermediates. Herein, surface-enhanced infrared absorption ...
18-Jan-2018 | Alex McSkimming; Thibault Cheisson; Patrick J. Carroll; Eric J. Schelter, Journal of the American Chemical Society, 2018
Journal of the American Chemical Society DOI: 10.1021/jacs.7b12318
18-Jan-2018 | Tao Liu; James T. Frith; Gunwoo Kim; Rachel N. Kerber; Nicolas Dubouis; Yuanlong Shao; Zigeng Liu; Pieter C. M. M. M ..., Journal of the American Chemical Society, 2018
The parasitic reactions associated with reduced oxygen species and the difficulty in achieving the high theoretical capacity have been major issues plaguing development of practical nonaqueous Li-O2 batteries. We hereby address the above issues by exploring the synergistic effect of ...
18-Jan-2018 | Chaohuang Chen; Yixin Luo; Liang Fu; Pinhong Chen; Yu Lan; Guosheng Liu, Journal of the American Chemical Society, 2018
Journal of the American Chemical Society DOI: 10.1021/jacs.7b11470
17-Jan-2018 | Xingyu Jiang; Philip Boehm; John F. Hartwig, Journal of the American Chemical Society, 2018
We report stereodivergent allylic substitution reactions of allylic esters with prochiral enolates derived from azaaryl acetamides and acetates to form products from addition of the enolates at the most substituted carbon of an allyl moiety with two catalysts, a chiral metallacyclic iridium ...