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1,035 Newest Publications in russian journal of general chemistry


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Reactions of methyl 3,3,3-trifluoro-2-(pyridin-2-ylimino)-propanoates with mono- and difunctional nucleophiles

20-Feb-2010 | V. B. Sokolov, A. Yu. Aksinenko, Russian Journal of General Chemistry, 2010

Reactions of methyl 3,3,3-trifluoro-2-(pyridin-2-ylimino)propanoates with such nucleophiles and 1,3-binucleophiles as methanol, p-toluidine, phenylhydrazine, diethyl phosphonate, 2-aminobut-2-enenitrile, benzamidine, and 4,5-dihydro-1,3-thiazol-2-amine led to the formation of various acyclic ...


Complexes of Cu(II) and Pd(II) with 2-R-1,3,11,11c-tetraazacyclopenta[c]phenanthrenes

20-Feb-2010 | S. B. Larionov, L. I. Myachina, E. G. Boguslavskii, R. V. Andreev, G. I. Borodkin, V. E. Shubin, Russian Journal of General Chemistry, 2010

Paramagnetic complexes CuL1SO4·0.5H2O, CuL2SO4·2H2O and diamagnetic Pd(HL2)Cl3 (L1 = 2-methyl-1,3,11,11c-tetraazacyclopenta[c]phenanthrene complex (L2 = 2-phenyl-1,3,11,11c-tetraazacyclopenta-[c]phenanthrene) were synthesized. The most probable structure of the complexes was suggested on the ...


Transformation of substituted 5-amino-1,3-oxazole-4-carbonitriles into new 3,4,5-triaminopyrazole derivatives

20-Feb-2010 | A. P. Kozachenko, O. V. Shablykin, A. N. Vasilenko, V. S. Brovarets, Russian Journal of General Chemistry, 2010

Reactions of accessible 5-alkylamino- and 5-arylamino-1,3-oxazole-4-carbonitriles with hydrazine hydrate on heating involved a complex transformation sequence resulting in the formation of 3,4,5-triaminopyrazole derivatives. The structure of the products was confirmed by their cyclocondensation ...


Synthesis and structure of fluoroalkyl containing lithium 1,3-diketonates

20-Feb-2010 | N. S. Boltacheva, V. I. Filyakova, E. F. Khmara, O. V. Koryakova, V. N. Charushin, Russian Journal of General Chemistry, 2010

Methods of synthesis and IR, mass, NMR 1H, 19F, 13C spectra as well as X-ray analysis of fluoroalkyl containing lithium 1,3-diketonates are reviewed.


Hydrosilylation of acetophenone with diphenylsilane in the presence of rhodium(I) complexes with chiral amines

20-Feb-2010 | V. M. Uvarov, D. A. de Vekki, V. P. Reshetilovskii, N. K. Skvortsov, Russian Journal of General Chemistry, 2010

New chiral rhodium complexes cis-[Rh(CO)2(RNH2)Cl] [RNH2 = (R)-(−)-cis-MyrtNH2, (R)-(−)-MenthylNH2, (R)-(+)-BornylNH2] were synthesized and their catalytic properties in reactions of hydrosilylation of acetophenone with diphenylsilane were studied. It was shown that the reaction products were ...


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