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852,936 Newest Publicationsrss
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03-Jul-2018 | Anderson José Lopes Catão; Alejandro López-Castillo, Journal of Environmental Monitoring, 2018
The degradation in water of the most widespread herbicide, glyphosate, is still under debate. Experimental disagreements on this process exist and there are only a few theoretical studies to support any conclusions. Moreover, the relationship between glyphosate and glycine is underestimated. ...
03-Jul-2018 | Lorenzo Biancalana; Lucinda K. Batchelor; Gianluca Ciancaleoni; Stefano Zacchini; Guido Pampaloni; Paul J. Dyson; Fa ..., Dalton Transactions, 2018
The carbonic anhydrase inhibitor acetazolamide (AcmH2) reacted with [(η6-p-cymene)RuCl(μ-Cl)]2 to afford [(η6-p-cymene)RuCl2(κN-AcmH2)], 1A, in near-quantitative yield. In methanol, 1A exists in equilibrium with 1B, being probably a coordination isomer, as established by VT 1H-EXSY NMR ...
03-Jul-2018 | Maria Frutos; Mar Gomez-Gallego; Elena A Giner; Miguel A. Sierra; Carmen Ramirez de Arellano, Dalton Transactions, 2018
Ir(III) and Rh(III)-mediated site-selective cage B–H and C–H bond activation in o-carboranylmethyl derivatives has been achieved. The selectivity of the reaction is related to the electron donating properties of the ligand. 1,2,3-triazole-Derivatives use the N2 position of the triazole ring to ...
03-Jul-2018 | Amit Sil; Sabyasachi Roy Chowdhury; Sabyashachi Mishra; Sanjib K Patra, Dalton Transactions, 2018
A series of arylene-vinylene π-conjugated terpyridyl ruthenium(II) complexes, [Ru(PPh3)2Cl(tpy-C6H4-CH=CH-Ar)][PF6] (1-4; tpy = 2,2':6',2''-terpyridyl where Ar = phenyl, tolyl, 1-naphthyl and 9-anthracenyl as substituents on 4′ position of tpy) have been synthesized and characterized by ...
03-Jul-2018 | Jiaxin Fan; Jack Yang; Anh Pham; Sean Li, Physical Chemistry Chemical Physics, 2018
The interactions between metals and two-dimensional materials, in particular, the adsorption energies, strongly determine the performances of rechargeable batteries. Previously, it has been demonstrated that heterostructures of two dimensional (2D) materials can lead to enhanced metal ...
03-Jul-2018 | Hirokazu Tanoue; Kazuma Inoue; Norifumi L. Yamada; Kohzo Ito; Syo Miyao; Takashi Ishizone; Hideaki Yokoyama, Soft Matter, 2018
A highly dense polymer brush was previously fabricated by the spontaneous segregation of amphiphilic diblock copolymers in an elastomer matrix into water and a hydrophobic polymer interface and named a ‘dynamic polymer brush’. We fabricated a lower critical solution temperature (LCST)-type ...
03-Jul-2018 | Jiulong Su; Jinhua Dong; Tetsuya Kitaguchi; Yuki Ohmuro-Matsuyama; Hiroshi Ueda, Analyst, 2018
Correction for ‘Noncompetitive homogeneous immunodetection of small molecules based on beta-glucuronidase complementation’ by Jiulong Su et al., Analyst, 2018, 143, 2096–2101.
03-Jul-2018 | Joshua Lipton-Duffin; Maryam Abyazisani; Jennifer MacLeod, Chemical Communication, 2018
Surface-catalyzed reactions provide a versatile route to synthesizing new 2D materials. Here, we show that the statistical nature of an activated reaction can lead to a diversity of intermolecular bonding motifs through partially-reacted molecules. With increasing annealing, we observe different ...
03-Jul-2018 | Yushi Bai; Agata Chotera; Olga Taran; Chen Liang; Gonen Ashkenasy; David G. Lynn, Chemical Society Reviews, 2018
Correction for ‘Achieving biopolymer synergy in systems chemistry’ by Yushi Bai et al., Chem. Soc. Rev., 2018, DOI: 10.1039/c8cs00174j.
03-Jul-2018 | Niels Tannert; Serkan Gökpinar; Emrah Hastürk; Sandra Nießing; Christoph Janiak, Dalton Transactions, 2018
Microwave-assisted dry-gel conversion (MW-DGC) combines advantages of concentrated reactants in DGC with fast heating by microwave irradiation. This novel combination allows to drastically decrease the amount of solvent needed for synthesis and reaction times with energy needed. Further, MW-DGC ...