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552 Newest Publications about the topic acrylates

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Palladium-catalyzed aerobic regio- and stereo-selective olefination reactions of phenols and acrylates via direct dehydrogenative C(sp2)–O cross-coupling

26-May-2018 | Yun-Bin Wu; Dan Xie; Zhong-Lin Zang; Cheng-He Zhou; Gui-Xin Cai, Chemical Communication, 2018

An efficient olefination protocol for the oxidative dehydrogenation of phenols and acrylates has been achieved using a palladium catalyst and O2 as the sole oxidant. This reaction exhibits high regio- and stereo-selectivity (E-isomers) with moderate to excellent isolated yields and a wide ...

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Modeling the free-radical polymerization of hexanediol diacrylate (HDDA): a molecular dynamics and graph theory approach

24-May-2018 | Ariana Torres-Knoop; Ivan Kryven; Verena Schamboeck; Piet D. Iedema, Soft Matter, 2018

In the printing, coating and ink industries, photocurable systems are becoming increasingly popular and multi-functional acrylates are one of the most commonly used monomers due to their high reactivity (fast curing). In this paper, we use molecular dynamics and graph theory tools to investigate ...

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Molecules, Vol. 23, Pages 979: In(III)-TMSBr-Catalyzed Cascade Reaction of Diarylalkynes with Acrylates for the Synthesis of Aryldihydronaphthalene Derivatives

23-Apr-2018 | Zhang, Qiu-Chi ; Zhang, Wen-Wei ; Shen, Liang ; Shen, Zhi-Liang ; Loh, Teck-Peng, Molecules, 2018

Molecules, Vol. 23, Pages 979: In(III)-TMSBr-Catalyzed Cascade Reaction of Diarylalkynes with Acrylates for the Synthesis of Aryldihydronaphthalene Derivatives Molecules doi: 10.3390/molecules23040979 Authors: Qiu-Chi Zhang Wen-Wei Zhang Liang Shen Zhi-Liang Shen Teck-Peng ...

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Drug delivery via anion exchange of salicylate decorating poly(meth)acrylates based on a pharmaceutical ionic liquid

15-Jan-2018 | Rafał Bielas; Dariusz Łukowiec; Dorota Neugebauer, New Journal of Chemistry, 2018

Amphiphilic polymer carriers were designed for the delivery of ionically bonded drugs. The ionic liquid, trimethylammonium methacrylate monomer, containing biologically active salicylate anions was selected for the preparation of copolymers via atom transfer radical polymerization (ATRP) with ...

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Tough and Tear‐Resistant Double‐Network Hydrogels Based on a Facile Strategy: Micellar Polymerization Followed by Solution Polymerization

09-Jan-2018 | Yu Zhao, Bing Hu Xia, Lei Wang, Run Jun Wang, Dan Ni Meng, Yang Liu, Jun Wei Zhou, Hui Qin Lian, Lei Zu, Xiu Guo Cui ..., Macromolecular Materials and Engineering, 2018

Abstract How to prepare a hydrogel with high strength and excellent tearing fracture energy is a problem faced by researchers. Here, tough and tear‐resistant double‐network hydrogels (Cx‐SMy gels) are successfully prepared via a facile strategy: micellar polymerization followed by solution ...

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Polymeric bile acid sequestrants: Review of design, in vitro binding activities, and hypocholesterolemic effects

24-Dec-2017 | Author(s): Eva Heřmánková, Aleš Žák, Lenka Poláková, Radka Hobzová, Róbert Hromádka, Jakub Širc, European Journal of Medicinal Chemistry, 2017

Publication date: 20 January 2018 Source:European Journal of Medicinal Chemistry, Volume 144 Author(s): Eva Heřmánková, Aleš Žák, Lenka Poláková, Radka Hobzová, Róbert Hromádka, Jakub Širc Polymeric bile acid sequestrants (BAS) have recently attracted much attention as ...

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Molecules, Vol. 22, Pages 2143: Novel Carbazole Skeleton-Based Photoinitiators for LED Polymerization and LED Projector 3D Printing

04-Dec-2017 | Al Mousawi, Assi ; Garra, Patxi ; Dumur, Frédéric ; Bui, Thanh-Tuan ; Goubard, Fabrice ; Toufaily, Joumana ; Hamieh, ..., Molecules, 2017

Molecules, Vol. 22, Pages 2143: Novel Carbazole Skeleton-Based Photoinitiators for LED Polymerization and LED Projector 3D Printing Molecules doi: 10.3390/molecules22122143 Authors: Assi Al Mousawi Patxi Garra Frédéric Dumur Thanh-Tuan Bui Fabrice Goubard Joumana ...

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Organocatalyzed photo‐controlled radical polymerization of semi‐fluorinated (meth)acrylates driven by visible light

14-Nov-2017 | Mao Chen, Honghong Gong, Yucheng Zhao, Xianwang Shen, Jun Lin, Angewandte Chemie International Edition, 2017

Fluorinated polymers are important materials that are widely used in many areas. Herein, we report the development of a metal‐free photo‐controlled radical polymerization of semi‐fluorinated (meth)acrylates with a new visible light absorbing organocatalyst. This method allows the production of a ...

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Electrochemically Mediated Reversible Addition–Fragmentation Chain-Transfer Polymerization

13-Oct-2017 | Yi Wang; Marco Fantin; Sangwoo Park; Eric Gottlieb; Liye Fu; Krzysztof Matyjaszewski, Macromolecules, 2017

An electrochemically mediated reversible addition–fragmentation chain-transfer polymerization (eRAFT) of (meth)acrylates was successfully carried out via electroreduction of either benzoyl peroxide (BPO) or 4-bromobenzenediazonium tetrafluoroborate (BrPhN2+) which formed aryl radicals, acting as ...

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Iodosylbenzene-Pseudohalide-Based Initiators for Radical Polymerization

12-Oct-2017 | Rajesh Kumar; Yakun Cao; Nicolay V. Tsarevsky, The Journal of Organic Chemistry, 2017

Iodosylbenzene reacts with various (pseudo)halides (trimethylsilyl azide or isocyanate or potassium azide, cyanate, and bromide) to yield unstable hypervalent iodine(III) compounds, PhIX2 (X = (pseudo)halide), that undergo rapid homolysis of the hypervalent I–X bonds and generate (pseudo)halide ...

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