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103 Newest Publications about the topic aluminum chloride

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Recycling and oligomerization activity of a Ni/Al‐catalyst in a biphasic system with ionic liquids

19-Oct-2016 | Prof. Dr. Arno Behr, Dr. Zeynep Bayrak, Güner Samli, Dilbar Yildiz, Vedat Korkmaz, Dr. Stefan Peitz, Dr. Guido Stochniol, Chemical Engineering & Technology, 2016

Abstract The catalyst decomposition in homogenous catalyzed reactions is a very important factor, which has been studied for the oligomerization of n‐butenes in a system of two liquid phases. A highly active catalyst NiCl2(PMe3)2 was investigated with a particular emphasis on long‐term ...

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Aluminum chloride promoted cross‐coupling of trisubstituted enol phosphates with organozinc reagents en route to stereoselective synthesis of tamoxifen and its analogues

18-Aug-2016 | Tomas Tobrman, Vladislav Kotek, Peter Polák, Hana Dvoáková, European Journal of Organic Chemistry, 2016

A new methodology for the stereoselective cross‐coupling reaction of aryl zinc chlorides with trisubstituted enol phosphates is described. The developed methodology requires aluminum chloride as a promoter, and the reaction conditions tolerate various functional groups. The observed reactivity ...

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Bio‐based plasticizer and thermoset polyesters: A green polymer chemistry approach

02-Jun-2016 | Mathew D. Rowe, Ersan Eyiler, Keisha B. Walters, Journal of Applied Polymer Science, 2016

ABSTRACT Renewable resource‐based polyesters, poly(trimethylene malonate) (PTM) and poly(trimethylene itaconate) (PTI), were synthesized from 1,3‐propanediol, malonic acid, and itaconic acid via melt polycondensation using green chemistry principles. Aluminum chloride, a Lewis acid, was used ...

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Aluminum Chloride Mediated Reactions of N-Alkylated Tosyl­hydrazones and Terminal Alkynes: A Regioselective Approach to 1,3,5-Trisubstituted Pyrazoles

24-May-2016 | Meng Tang; Yun Wang; Hu Wang; Yuanfang Kong, Synthesis, 2016

SynthesisDOI: 10.1055/s-0035-1561646 Aluminum chloride mediated reactions of N-alkylated tosylhydrazones and terminal alkynes are reported. The protocol is applied to a wide range of substrates, and demonstrates excellent functional group tolerance. A series of 1,3,5-trisubstituted pyrazoles is ...

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Controlling the morphology of calcium sulfate hemihydrate using aluminum chloride as a habit modifier

09-Feb-2016 | Wenpeng Zhao; Chuanhui Gao; Guangyu Zhang; Jun Xu; Chuanxing Wang; Yumin Wu, New Journal of Chemistry, 2016

The morphology and aspect ratio of calcium sulfate hemihydrate (HH) are successfully controlled using AlCl3 as a morphology modifier in the hydrothermal synthesis process. As the concentration of AlCl3 is increased from 0 to 7.5 × 10−2 mol L−1, the crystal length decreases from 130 μm to 0.1–0.3 ...

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Preparation of Poly(ether ketone)s Derived from 2,5-Furandicarboxylic Acid by Polymerization in Ionic Liquid

03-Feb-2016 | Yusuke Kanetaka; Shinichi Yamazaki; Kunio Kimura, Macromolecules, 2016

Aromatic poly(ether ketone)s were synthesized by the Friedel–Crafts polymerization of 2,5-furandicarbonyl dichloride prepared from biomass and petroleum-based aromatic ethers such as diphenyl ether and 1,4-diphenoxybenzene with aluminum chloride (AlCl3). The polymerizations in common molecular ...

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The Interplay of Al and Mg Speciation in Advanced Mg Battery Electrolyte Solutions

22-Dec-2015 | Kimberly A. See; Karena W. Chapman; Lingyang Zhu; Kamila M. Wiaderek; Olaf J. Borkiewicz; Christopher J. Barile; Pet ..., Journal of the American Chemical Society, 2015

Mg batteries are an attractive alternative to Li-based energy storage due to the possibility of higher volumetric capacities with the added advantage of using sustainable materials. A promising emerging electrolyte for Mg batteries is the magnesium aluminum chloride complex (MACC) which shows ...

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Aluminum Chloride Mediated Alkynylation of Boron Subphthalocyanine Chloride Using Trimethylsilyl-Capped Acetylenes

18-Dec-2015 | Henrik Gotfredsen; Martyn Jevric; Søren L. Broman; Anne U. Petersen; Mogens Brøndsted Nielsen, The Journal of Organic Chemistry, 2015

The Journal of Organic Chemistry DOI: 10.1021/acs.joc.5b02719

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Phase Equilibrium Study of the AlCl3–CaCl2–H2O System for the Production of Aluminum Chloride Hexahydrate from Ca-Rich Flue Ash

10-Nov-2015 | Junfeng Wang; Camille Petit; Xiangping Zhang; Shian Cui, Journal of Chemical & Engineering Data, 2015

The study of the solid–liquid phase equilibrium for the AlCl3–CaCl2–H2O system is of significance to separate aluminum chloride hexahydrate from the leachate obtained by the reaction of Ca-rich fly ash and a waste hydrochloride from chemical plant. The phase equilibrium data for the binary ...

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Elucidating the Structure of the Magnesium Aluminum Chloride Complex electrolyte for Magnesium-ion batteries

03-Nov-2015 | Pieremanuele Canepa; Saivenkataraman Jayaraman; Lei Cheng; Nav Rajput; William Davidson Richards; Gopalakrishnan Sa ..., Energy & Environmental Science, 2015

Non-aqueous Mg-ion batteries offer a promising way to overcome safety, costs, and energy density limitations of state-of-the-art Li-ion battery technology. We present a rigorous analysis of the Magnesium Aluminum Chloro Complex (MACC) in THF, one of the few electrolytes that can reversibly plate ...

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