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982 Newest Publications about the topic cerium


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Redox-enhanced hemilability of the tris(tert-butoxy)siloxy ligand at cerium

03-Jul-2018 | Jochen Friedrich; Yusen Qiao; Caecilia Maichle-moessmer; Eric J Schelter; Reiner Anwander, Dalton Transactions, 2018

The stabilizing effect of the tris(tert-butoxy)silyoxy ligand on cerium(IV) is revealed by electrochemical and computation methods as well as targeted redox chemistry. Ceric homoleptic complex Ce[OSi(OtBu)3]4 was obtained by the reaction of [Et4N]2[CeCl6] with NaOSi(OtBu)3 at ambient temperature ...


Structural, optical and X-ray attenuation properties of Tb3+:BaxCe1-xF3-x (x=0.18 – 0.48) nanospheres synthesized in polyol medium

05-Jun-2018 | Daniel Gonzalez-Mancebo; Ana Isabel Becerro; Cécile Genevois; Mathieu Allix; Ariadna Corral; Angel Parrado-Gall ..., Dalton Transactions, 2018

Uniform Ba0.18Ce0.82F2.82 nanospheres have been obtained after aging at 120 ºC for 20 hours a solution of barium and cerium nitrates and sodium tetrafluoroborate in a mixture of ethylene glycol and water. The spheres diameter could be tailored from 65 nm to 80 nm by varying the NaBF4 ...


Ultra-fast precipitation of transient amorphous cerium oxalate in concentrated nitric acid media

29-May-2018 | Isaac Rodríguez-Ruiz; Sophie Charton; Dimitri Radajewski; Thomas Bizien; Sébastien Teychené, CrystEngComm, 2018

Amorphous cerium oxalate precipitation is here characterized and reported for the first time as a primary nucleating transient precursor for a more stable crystalline hydrated phase, at high supersaturations and in strong acid solutions. Preliminary results point out an initial binodal phase ...


Amorphous saturated cerium–tungsten–titanium oxide nanofiber catalysts for NOx selective catalytic reaction

29-May-2018 | Apiwat Dankeaw; Fabrizio Gualandris; Rafael Hubert Silva; Kion Norrman; Mads Gudik-Sørensen; Kent Kammer Hansen ..., New Journal of Chemistry, 2018

Herein for the first time, Ce0.184W0.07Ti0.748O2−δ nanofibers are prepared by electrospinning to serve as a catalyst in the selective catalytic reduction (SCR) process. The addition of cerium is proven to inhibit crystallization of TiO2, yielding an amorphous TiOx-based solid solution stable up ...


Unique and contrasting structures of homoleptic lanthanum(III) and cerium(III) 3,5-dimethylpyrazolates

24-May-2018 | Daniel Werner; Uwe Bayer; Nazli E. Rad; Peter C. Junk; Glen B. Deacon; Reiner Anwander, Dalton Transactions, 2018

Homoleptic [La(Me2pz)3]n (Me2pz = 3,5-dimethylpyrazolato) is a μ–η2:η5-Me2pz coordination polymer with 12-coordinate La atoms in an unusual η5:η5 Me2pz sandwich, whilst the cerium congener forms a molecular tetrametallic cage [Ce4(Me2pz)12] featuring six different Me2pz coordination modes.


Materials, Vol. 11, Pages 250: Cerium Addition Improved the Dry Sliding Wear Resistance of Surface Welding AZ91 Alloy

06-Feb-2018 | Chen, Qingqiang ; Zhao, Zhihao ; Zhu, Qingfeng ; Wang, Gaosong ; Tao, Kai, Materials, 2018

Materials, Vol. 11, Pages 250: Cerium Addition Improved the Dry Sliding Wear Resistance of Surface Welding AZ91 Alloy Materials doi: 10.3390/ma11020250 Authors: Qingqiang Chen Zhihao Zhao Qingfeng Zhu Gaosong Wang Kai Tao In this study, the effects of cerium (Ce) addition on ...


Molecules, Vol. 23, Pages 37: A Facile Route toward the Increase of Oxygen Content in Nanosized Zeolite by Insertion of Cerium and Fluorinated Compounds

24-Jan-2018 | Komaty, Sarah ; Anfray, Clément ; Zaarour, Moussa ; Awala, Hussein ; Ruaux, Valérie ; Valable, Samuel ; Mintova, Sve ..., Molecules, 2018

Molecules, Vol. 23, Pages 37: A Facile Route toward the Increase of Oxygen Content in Nanosized Zeolite by Insertion of Cerium and Fluorinated Compounds Molecules doi: 10.3390/molecules23020037 Authors: Sarah Komaty Clément Anfray Moussa Zaarour Hussein Awala Valérie ...


Fabrication of ultralong ceria nanobelts via a coordination polymer precursor method

23-Jan-2018 | Yuan Li; Hong-Hong Zou; Zhiwei Qiao; Yuan-Yuan Liao; Lei Wang; Shengliang Zhong, New Journal of Chemistry, 2018

Ultralong cerium-based coordination polymer (Ce-CP) nanobelts have been prepared from benzene-1,3-dicarboxylic acid (1,3-H2BDC) and Ce(NO3)3 via a facile solvothemal method, employing cheap and non-toxic mixture of ethanol and water as solvent. The products were well characterized and analyzed. ...


A new strongly paramagnetic cerium-containing microporous MOF for CO2 fixation under ambient conditions

17-Jan-2018 | Sabuj Kanti Das; Sauvik Chatterjee; Subhajit Bhunia; Abhishake Mondal; Partha Mitra; Vandana Kumari; Anirban Pradhan ..., Dalton Transactions, 2018

Metal organic frameworks (MOFs) bearing multicarboxylate linkers are in great demand for designing robust heterogeneous catalysts. A new microporous Ce(iii)-based metal organic framework (Ce2NDC3) has been synthesized under solvothermal conditions, which showed strong paramagnetism and a CO2 ...


Comprehensive Understanding of the Spatial Configurations of CeO2 in NiO for the Electrocatalytic Oxygen Evolution Reaction: Embedded or Surface‐Loaded

17-Jan-2018 | Wei Gao, Zhaoming Xia, Fangxian Cao, Johnny C. Ho, Zheng Jiang, Yongquan Qu, Advanced Functional Materials, 2018

Abstract Introducing cerium (Ce) species into electrocatalysts has been recently developed as an effective approach to improve their oxygen evolution reaction (OER) performance. Importantly, the spatial distribution of Ce species in the hosts can determine the availability of Ce species either ...


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