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1,096 Newest Publications about the topic cyanide

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A [FeIII(Tp)(CN)3]− scorpionate-based complex as a building block for designing ion storage hosts (Tp: hydrotrispyrazolylborate)

25-May-2018 | Juan-Ramón Jiménez; Akira Sugahara; Masashi Okubo; Atsuo Yamada; Lise-Marie Chamoreau; Laurent Lisnard; Ro ..., Chemical Communication, 2018

Using a scorpionate-based complex, [FeIII(Tp)(CN)3]−, as a building block, a new cyanide-based molecular material [{FeIII(Tp)(CN)3}2NiII(H2O)2]·4H2O (1), which can be viewed as a lower dimensional model of Prussian blue analogues, was investigated as a lithium-ion storage host.

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Syntheses, crystal structures, and magnetic properties of cyanide-bridged complexes trans-RuII(dppe)2(CN)2(FeIIIX3)2 (X = Cl and Br)

25-May-2018 | Yong Wang; Xiaoquan Zhu; Tianlu Sheng; Xintao Wu, New Journal of Chemistry, 2018

The syntheses, crystal structures and electronic absorption spectra of cyanide-bridged complexes trans-RuII(dppe)2(CN)2(FeIIIX3)2 (X = Cl, 2; X = Br, 3; dppe = 1,2-bis(diphenylphosphino)ethane) and their parent trans-RuII(dppe)2(CN)2 (1) were reported. Both the crystal structural data and MMCT ...

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Cyanosilylation of Aldehydes Catalyzed by Iron(iii) Arylhydrazone-β-Diketone Complexes

20-Feb-2018 | ie=edge, Australian Journal of Chemistry, 2018

Atash V. Gurbanov, Abel M. Maharramov, Fedor I. Zubkov, Alexander M. Saifutdinov, Firudin I. Guseinov - Volume 71(3) Mononuclear iron(iii)-arylhydrazone-β-diketone complexes act as homogeneous catalysts for the cyanosilylation of aldehydes with trimethylsilyl cyanide, leading to cyanohydrin ...

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A fluorescent turn-on probe for cyanide anion detection based on an AIE active cobalt(II) complex

23-Jan-2018 | Moustafa T. Gabr; F. Christopher Pigge, Dalton Transactions, 2018

A new tetradentate polypyridine ligand that displays aggregation induced emission (AIE) characteristics has been synthesized. A coordination complex with CoCl2 has been prepared and characterized by X-ray crystallography. The Co(ii) complex retains the AIE activity of the ligand in aqueous ...

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A benzopyrylium–phenothiazine conjugate of a flavylium derivative as a fluorescent chemosensor for cyanide in aqueous media and its bioimaging

20-Jan-2018 | Sanchita Mondal; Syed Samim Ali; Srimanta Manna; Kalipada Maiti; Md. Raihan Uddin; Sukhendu Mandal; Debasish Mandal; ..., New Journal of Chemistry, 2018

A new benzopyrylium–phenothiazine conjugate (BP) of a flavylium derivative was synthesized and characterized. The probe BP was shown to be selective and sensitive for CN− among the 17 anions and biothiols studied in HEPES buffer medium by fluorescence, absorption, and visual color change. The ...

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A benzopyrylium–phenothiazine conjugate of a flavylium derivative as a fluorescent chemosensor for cyanide in aqueous media and its bioimaging

20-Jan-2018 | Sanchita Mondal; Syed Samim Ali; Srimanta Manna; Kalipada Maiti; Md. Raihan Uddin; Sukhendu Mandal; Debasish Mandal; ..., New Journal of Chemistry, 2018

A new benzopyrylium–phenothiazine conjugate (BP) of a flavylium derivative was synthesized and characterized. The probe BP was shown to be selective and sensitive for CN− among the 17 anions and biothiols studied in HEPES buffer medium by fluorescence, absorption, and visual color change. The ...

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Synthesis of 1,2,3‐fused indole polyheterocycles via copper catalyzed cascade reaction

18-Jan-2018 | Ching-Fa Yao, European Journal of Organic Chemistry, 2018

A one‐pot synthesis of 1,2,3‐fused indole polyheterocycle starting from 2‐iodobenzamide and 2‐iodobenzyl cyanide in the presence of coppoer catalyst is described. The cascade process that involves one C‐C and thre C‐N bond formation efficiently has a broad substrate scope.

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A new Mo(IV) complex with the pentadentate (N3O2) Schiff-base ligand: the first non-cyanide pentagonal–bipyramidal paramagnetic 4d complex

17-Jan-2018 | V. S. Mironov; T. A. Bazhenova; Yu. V. Manakin; K. A. Lyssenko; A. D. Talantsev; E. B. Yagubskii, Dalton Transactions, 2018

A heptacoordinate complex [MoIV(DAPBH)Cl2] (H2DAPBH is 1,1′-(pyridine-2,6-diyl)bis(ethan-1-yl-1-ylidene)dibenzohydrazine) has been synthesized and characterized structurally and magnetically. It exhibits a slightly distorted pentagonal bipyramidal geometry and reveals paramagnetic behaviour ...

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Drastic Redox Shift and Electronic Structural Changes of a Manganese(III)-Salen Oxidation Catalyst upon Reaction with Hydroxide and Cyanide Ion

11-Jan-2018 | Takuya Kurahashi, Inorganic Chemistry, 2018

Flexible redox properties of a metal complex are important for redox catalysis. The present study shows that the reaction of a manganese(III) salen complex, which is a well-known oxidation catalyst, with hydroxide ion gives a transient manganese(III) species with drastically lowered redox ...

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Drastic Redox Shift and Electronic Structural Changes of a Manganese(III)-Salen Oxidation Catalyst upon Reaction with Hydroxide and Cyanide Ion

11-Jan-2018 | Takuya Kurahashi, Inorganic Chemistry, 2018

Flexible redox properties of a metal complex are important for redox catalysis. The present study shows that the reaction of a manganese(III) salen complex, which is a well-known oxidation catalyst, with hydroxide ion gives a transient manganese(III) species with drastically lowered redox ...

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