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3,196 Newest Publications about the topic hydration

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Original behavior of pore water radiolysis in cement-based materials containing sulfide: Coupling between experiments and simulations

27-May-2018 | Author(s): P. Bouniol, W. Guillot, V. Dauvois, W. Dridi, S. Le Caër, Radiation Physics and Chemistry, 2018

Publication date: September 2018 Source:Radiation Physics and Chemistry, Volume 150 Author(s): P. Bouniol, W. Guillot, V. Dauvois, W. Dridi, S. Le Caër Blended cements with high content of blast furnace slag (CEM III/C) can be used for nuclear waste conditioning because of their ...

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Hydrogen bond basicity of ionic liquids and molar entropy of hydration of salts as major descriptors in the formation of aqueous biphasic systems

27-May-2018 | Helena Passos; Teresa B. V. Dinis; Ana Filipa M. Cláudio; Mara G. Freire; João A. P. Coutinho, Physical Chemistry Chemical Physics, 2018

Aqueous biphasic systems (ABS) composed of ionic liquids (ILs) and conventional salts have been largely investigated and successfully used in separation processes, for which the determination of the corresponding ternary phase diagrams is a prerequisite. However, due the large number of ILs that ...

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Materials, Vol. 11, Pages 900: Waste-Based Pervious Concrete for Climate-Resilient Pavements

27-May-2018 | Ho, Hsin-Lung ; Huang, Ran ; Hwang, Lih-Chuan ; Lin, Wei-Ting ; Hsu, Hui-Mi, Materials, 2018

Materials, Vol. 11, Pages 900: Waste-Based Pervious Concrete for Climate-Resilient Pavements Materials doi: 10.3390/ma11060900 Authors: Hsin-Lung Ho Ran Huang Lih-Chuan Hwang Wei-Ting Lin Hui-Mi Hsu For the sake of environmental protection and circular economy, cement ...

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Hydration and ion association of La3+ and Eu3+ salts in aqueous solution

26-May-2018 | Sergej Friesen; Sebastian Krickl; Magdalena Luger; Andreas Nazet; Glenn Hefter; Richard Buchner, Physical Chemistry Chemical Physics, 2018

Aqueous solutions of five lanthanide salts: LaCl3, La(NO3)3, La2(SO4)3, Eu(NO3)3 and Eu2(SO4)3 have been studied at 25 °C by dielectric relaxation spectroscopy over the frequency range 0.05 ≤ ν/GHz ≤ 89. Detailed analysis of the solvent-related modes located at higher frequencies showed that both ...

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Carbonate and carbonate anion radicals in aqueous solutions exist as CO3(H2O)62− and CO3(H2O)6˙− respectively: the crucial role of the inner hydration sphere of anions in explaining their properties

26-May-2018 | Shmuel Zilberg; Amir Mizrahi; Dan Meyerstein; Haya Kornweitz, Physical Chemistry Chemical Physics, 2018

An effort to reproduce the chemical and physical properties of carbonate and carbonate anion radicals in aqueous solutions by DFT proves that one has to include an inner hydration sphere of six water molecules for both anions. Application of the SMD model to CO3(H2O)62− and CO3(H2O)6˙− enables ...

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Charge and hydration structure of dendritic polyelectrolytes: molecular simulations of polyglycerol sulphate

26-May-2018 | Rohit Nikam; Xiao Xu; Matthias Ballauff; Matej Kanduč; Joachim Dzubiella, Soft Matter, 2018

Macromolecules based on dendritic or hyperbranched polyelectrolytes have been emerging as high potential candidates for biomedical applications. Here we study the charge and solvation structure of dendritic polyglycerol sulphate (dPGS) of generations 0 to 3 in aqueous sodium chloride solution by ...

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Mechanism of protein–RNA recognition: analysis based on the statistical mechanics of hydration

25-May-2018 | Tomohiko Hayashi; Tomoaki Matsuda; Takashi Nagata; Masato Katahira; Masahiro Kinoshita, Physical Chemistry Chemical Physics, 2018

We investigate the RBD1–r(GUAGU) binding as a case study using all-atom models for the biomolecules, molecular models for water, and the currently most reliable statistical–mechanical method. RBD1 is one of the RNA-binding domains of mammalian Musashi1 (Msi1), and r(GUAGU) contains the minimum ...

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Hydration and alkoxylation of alkynes catalyzed by NHC–Au–OTf

25-May-2018 | Mattia Gatto; Walter Baratta; Paola Belanzoni; Leonardo Belpassi; Alessandro Del Zotto; Francesco Tarantelli; Daniel ..., Green Chemistry, 2018

The NHC–Au–OTf [NHC = 1,3-bis(2,6-di-isopropylphenyl)-imidazol-2-ylidene] catalyst was tested in the alkoxylation and hydration of alkynes in a wide set of neoteric solvents for the first time. We found that most of these solvents (ethyl lactate, glycerol, propylene carbonate, d-limonene, ...

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Hydration and alkoxylation of alkynes catalyzed by NHC–Au–OTf

25-May-2018 | Mattia Gatto; Walter Baratta; Paola Belanzoni; Leonardo Belpassi; Alessandro Del Zotto; Francesco Tarantelli; Daniel ..., Green Chemistry, 2018

The NHC–Au–OTf [NHC = 1,3-bis(2,6-di-isopropylphenyl)-imidazol-2-ylidene] catalyst was tested in the alkoxylation and hydration of alkynes in a wide set of neoteric solvents for the first time. We found that most of these solvents (ethyl lactate, glycerol, propylene carbonate, d-limonene, ...

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Entropy connects water structure and dynamics in protein hydration layer

24-May-2018 | Jayangika N. Dahanayake; Katie R. Mitchell-Koch, Physical Chemistry Chemical Physics, 2018

The enzyme Candida Antarctica lipase B (CALB) serves here as a model for understanding connections among hydration layer dynamics, solvation shell structure, and protein surface structure. The structure and dynamics of water molecules in the hydration layer were characterized for regions of the ...

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