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6,972 Newest Publications about the topic intermediates

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Molecules, Vol. 23, Pages 1582: Triorganoindium Reagents in Rh-Catalyzed C–H Activation/C–C Cross-Coupling Reactions of 2-Arylpyridines

29-Jun-2018 | Riveiros, Ricardo ; Tato, Rubén ; Pérez Sestelo, José ; Sarandeses, Luis A., Molecules, 2018

Molecules, Vol. 23, Pages 1582: Triorganoindium Reagents in Rh-Catalyzed C–H Activation/C–C Cross-Coupling Reactions of 2-Arylpyridines Molecules doi: 10.3390/molecules23071582 Authors: Ricardo Riveiros Rubén Tato José Pérez Sestelo Luis A. Sarandeses The activation of ...

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Conformational control and DNA-binding mechanism of the metazoan origin recognition complex [Biochemistry]

26-Jun-2018 | Franziska Bleichert; Alexander Leitner; Ruedi Aebersold; Michael R. Botchan; James M. Berger, Proceedings of the National Academy of Sciences current issue, 2018

The onset of chromosomal DNA replication relies on dedicated initiator proteins to chaperone ring-shaped helicases onto DNA. In most eukaryotes, initiators are multisubunit protein complexes that require ATP to bind DNA and to aid helicase recruitment and loading. Although structural studies have ...

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Roles of Gag-RNA interactions in HIV-1 virus assembly deciphered by single-molecule localization microscopy [Cell Biology]

26-Jun-2018 | Yantao Yang; Na Qu; Jie Tan; Muaz N. Rushdi; Christopher J. Krueger; Antony K. Chen, Proceedings of the National Academy of Sciences current issue, 2018

Single-molecule localization microscopy (SMLM) is useful for deciphering dynamic organizations of structures densely labeled by specific proteins in the cellular context with nanoscopic resolution not attainable by conventional imaging tools. Here we employed SMLM to investigate the mechanism by ...

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Chemically Controlled Crystal Growth of (CH3NH3)2AgInBr6

20-Jun-2018 | T. Thao Tran; Michael A Quintero; Kathryn E. Arpino; Zachary A Kelly; Jessica R. Panella; Xiaoping Wang; Tyrel M McQueen, CrystEngComm, 2018

We report the successful crystal growth of a previously unknown mixed-metal organic compound (CH3NH3)2AgInBr6. This phase, which is not obtained by direct combination of reactants, is crystallized through the use of Pb2+ (from CH3NH3PbBr3) to modulate the soluble intermediates and force formation ...

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Morphogenesis of anisotropic nanoparticles: self-templating via non-classical, fibrillar Cd2Se intermediates

20-Jun-2018 | Daniel Wurmbrand; Jörg Wolfram Anselm Fischer; Rose Rosenberg; Klaus Boldt, Chemical Communication, 2018

A fibrillar, polymeric intermediate (Cd2Se)n was isolated from the synthesis of CdSe nanorods, which suggests that the reactants themselves can template anisotropic growth. It is shown that high monomer concentration is the principal factor favouring this reaction pathway. The intermediate is ...

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Oxygen Activation at a Dicobalt Centre of a Dipyridylethane Naphthyridine Complex

20-Jun-2018 | Casey Brodsky; Guillaume Passard; Andrew Ullman; David Jaramillo; Eric D Bloch; Michael X. Huynh; David Gygi; Cyrill ..., Dalton Transactions, 2018

The mechanism of oxygen activation at a dicobalt bis-μ-hydroxo core is probed by the implementation of synthetic methods to isolate reaction intermediates. Reduction of a dicobalt(III,III) core ligated by the polypyridyl ligand dipyridylethane naphthyridine (DPEN) by two electrons and subsequent ...

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Molecules, Vol. 23, Pages 1493: Synthesis and Reactions of α-Hydroxyphosphonates

20-Jun-2018 | Rádai, Zita ; Keglevich, György, Molecules, 2018

Molecules, Vol. 23, Pages 1493: Synthesis and Reactions of α-Hydroxyphosphonates Molecules doi: 10.3390/molecules23061493 Authors: Zita Rádai György Keglevich This review summarizes the main synthetic routes towards α-hydroxyphosphonates that are known as enzyme ...

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Time-Resolved FTIR Study of Light-Driven Sodium Pump Rhodopsins

20-Jun-2018 | Hui-Fen Chen; Keiichi Inoue; Hikaru Ono; Rei Abe-Yoshizumi; Akimori Wada; Hideki Kandori, Physical Chemistry Chemical Physics, 2018

Light-driven sodium ion pump rhodopsin (NaR) is a new functional class of microbial rhodopsin. A previous flash photolysis study of Krokinobacter eikastus rhodopsin 2 (KR2) revealed the presence of three kinetically distinct intermediates: K, L/M, and O. Previous low-temperature Fourier-transform ...

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Molecules, Vol. 23, Pages 1457: Phosphorus Pentachloride Promoted gem-Dichlorination of 2′- and 3′-Deoxynucleosides

15-Jun-2018 | da Paixao Soares, Fabio ; Groaz, Elisabetta ; Herdewijn, Piet, Molecules, 2018

Molecules, Vol. 23, Pages 1457: Phosphorus Pentachloride Promoted gem-Dichlorination of 2′- and 3′-Deoxynucleosides Molecules doi: 10.3390/molecules23061457 Authors: Fabio da Paixao Soares Elisabetta Groaz Piet Herdewijn Halogen substitution at various positions of canonical ...

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Molecules, Vol. 23, Pages 1432: Membrane Fatty Acid Composition and Cell Surface Hydrophobicity of Marine Hydrocarbonoclastic Alcanivorax borkumensis SK2 Grown on Diesel, Biodiesel and Rapeseed Oil as Carbon Sources

13-Jun-2018 | Konieczna, Maria ; Olzog, Martin ; Naether, Daniela J.; Chrzanowski, Łukasz ; Heipieper, Hermann J., Molecules, 2018

Molecules, Vol. 23, Pages 1432: Membrane Fatty Acid Composition and Cell Surface Hydrophobicity of Marine Hydrocarbonoclastic Alcanivorax borkumensis SK2 Grown on Diesel, Biodiesel and Rapeseed Oil as Carbon Sources Molecules doi: 10.3390/molecules23061432 Authors: Maria ...

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