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97 Newest Publications about the topic krypton

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S[middle dot][middle dot][middle dot]S and S[middle dot][middle dot][middle dot]P chalcogen bonding in solution: A cryospectroscopic study of the complexes of 2,2,4,4-tetrafluoro-1,3-dithietane with dimethyl sulfide and trimethylphosphine.

30-May-2018 | Yannick Geboes; Elias De Vos; Wouter A. Herrebout, New Journal of Chemistry, 2018

In this combined experimental and computational study the complexes formed between 2,2,4,4-tetrafluoro-1,3-dithiethane (C2F4S2) and the Lewis bases dimethyl sulfide (DMS) and trimethylphosphine (TMP) are studied using infrared spectroscopy of solutions in liquid krypton. For C2F4S2 and DMS, ab ...

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General strategies for effective capture and separation of noble gases by metal–organic frameworks

25-May-2018 | Hao Wang; Jing Li, Dalton Transactions, 2018

In this frontier article, we provide a brief overview of recent progress in capture and separation of noble gases by microporous metal–organic framework-based adsorbents, with an emphasis on xenon and krypton. Our discussions include separation mechanisms and strategies applied to enhance the MOF ...

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Sensors, Vol. 18, Pages 1436: Investigating the Strain, Temperature and Humidity Sensitivity of a Multimode Graded-Index Perfluorinated Polymer Optical Fiber with Bragg Grating

05-May-2018 | Zheng, Yulong ; Bremer, Kort ; Roth, Bernhard, Sensors, 2018

Sensors, Vol. 18, Pages 1436: Investigating the Strain, Temperature and Humidity Sensitivity of a Multimode Graded-Index Perfluorinated Polymer Optical Fiber with Bragg Grating Sensors doi: 10.3390/s18051436 Authors: Yulong Zheng Kort Bremer Bernhard Roth In this work we ...

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IJMS, Vol. 19, Pages 1127: In Vitro and In Vivo Osteogenic Activity of Titanium Implants Coated by Pulsed Laser Deposition with a Thin Film of Fluoridated Hydroxyapatite

10-Apr-2018 | Chen, Luyuan ; Komasa, Satoshi ; Hashimoto, Yoshiya ; Hontsu, Shigeki ; Okazaki, Joji, International Journal of Molecular Sciences, 2018

IJMS, Vol. 19, Pages 1127: In Vitro and In Vivo Osteogenic Activity of Titanium Implants Coated by Pulsed Laser Deposition with a Thin Film of Fluoridated Hydroxyapatite International Journal of Molecular Sciences doi: 10.3390/ijms19041127 Authors: Luyuan Chen Satoshi Komasa Yoshiya ...

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Sustainability, Vol. 9, Pages 1222: Experimental and Numerical Research of the Thermal Properties of a PCM Window Panel

12-Jul-2017 | Koláček, Martin ; Charvátová, Hana ; Sehnálek, Stanislav, Sustainability, 2017

This paper reports the experimental and simulation analysis of a window system incorporating Phase Change Materials (PCMs). In this study, the latent heat storage material is exploited to increase the thermal mass of the building component. A PCM-filled window can increase the possibilities of ...

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Superelectrophilic Behavior of an Anion Demonstrated by the Spontaneous Binding of Noble Gases to [B12Cl11]−

31-May-2017 | Markus Rohdenburg, Martin Mayer, Max Grellmann, Carsten Jenne, Tobias Borrmann, Florian Kleemiss, Vladimir A. Azov, ..., Angewandte Chemie International Edition, 2017

Abstract It is common and chemically intuitive to assign cations electrophilic and anions nucleophilic reactivity, respectively. Herein, we demonstrate a striking violation of this concept: The anion [B12Cl11]− spontaneously binds to the noble gases (Ngs) xenon and krypton at room temperature ...

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Effect of Fluorination on the Competition of Halogen Bonding and Hydrogen Bonding: Complexes of Fluoroiodomethane with Dimethyl Ether and Trimethylamine

18-May-2017 | Yannick Geboes; Frank De Proft; Wouter A. Herrebout, Journal of Physical Chemistry A, 2017

To further rationalize the competition between halogen and hydrogen bonding, a combined experimental and theoretical study on the weakly bound molecular complexes formed between the combined halogen bond/hydrogen bond donor fluoroiodomethane and the Lewis bases dimethyl ether and trimethylamine ...

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Effect of noncovalent interactions on vibronic transitions: An experimental and theoretical study of the C2H···CO2 complex

23-Jan-2017 | Sergey V. Ryazantsev, Riccardo Tarroni, Vladimir I. Feldman, Leonid Khriachtchev, ChemPhysChem, 2017

We report on the experimental and theoretical infrared spectrum of the C2H···CO2 complex. This complex was prepared by UV photochemistry of propiolic acid (HC3OOH) in argon and krypton matrices. The experimental bands of C2H in the C2H···CO2 complex are blue‐shifted from those of C2H monomer. ...

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Coordination of KrF2 to a Naked Metal Cation, Mg2+

12-Jan-2017 | Matic Lozinšek, Hélène P. A. Mercier, David S. Brock, Boris Žemva, Gary J. Schrobilgen, Angewandte Chemie International Edition, 2017

Abstract Examples of coordination compounds in which KrF2 functions as a ligand are very rare. In contrast, XeF2 provides a rich coordination chemistry with a variety of main‐group and transition metal cations. The reactions of Mg(AsF6)2 and KrF2 in HF or BrF5 solvent have afforded ...

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Fragmentation of KrN+ clusters after electron impact ionization. Short-time dynamics simulations and approximate multi-scale treatment.

20-Dec-2016 | Ivan Jan Janeček; Pavel Naar; Martin Stachon; Rene Kalus; Florent Xavier Gadea, Physical Chemistry Chemical Physics, 2016

Post-ionization fragmentation of small ionic krypton clusters, KrN+(N = 3 - 13), has been investigated using a semiclassical non-adiabatic dynamics approach consisting of classical treatment of atomic nuclei and full quantum treatment of electrons, and an extended diatomics-in-molecules model ...

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