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2,348 Newest Publications about the topic metal organic frameworks

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Direct water-based synthesis and characterization of new Zr/Hf-MOFs with dodecanuclear clusters as IBU

03-Jul-2018 | Steve Waitschat; Helge Reinsch; Merve Arpacioglu; Norbert Stock, CrystEngComm, 2018

Two new metal-organic framework compounds of composition [M12(μ3-O)8(μ3-OH)8(μ-OH)6(OH)6(H2O)6(APDC)6], with M = Zr and Hf denoted as M-CAU-39, containing the azopyridinedicarboxylate ion (APDC2-) as a new linker, were obtained by a water based synthesis. The crystal structure was determined from ...

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Microwave-assisted dry-gel conversion - a new sustainable route for the rapid synthesis of metal-organic frameworks with solvent re-use

03-Jul-2018 | Niels Tannert; Serkan Gökpinar; Emrah Hastürk; Sandra Nießing; Christoph Janiak, Dalton Transactions, 2018

Microwave-assisted dry-gel conversion (MW-DGC) combines advantages of concentrated reactants in DGC with fast heating by microwave irradiation. This novel combination allows to drastically decrease the amount of solvent needed for synthesis and reaction times with energy needed. Further, MW-DGC ...

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Hydrogen-bonded organic frameworks: design, structures and potential applications

03-Jul-2018 | Jie Luo; Jia-Wei Wang; Ji-Hong Zhang; Shan Lai; Di-Chang Zhong, CrystEngComm, 2018

Hydrogen-bonded organic frameworks (HOFs), a new type of porous material following the metal-organic frameworks (MOFs), covalent organic frameworks (COFs), etc., have emerged as one of the promising candidates in diverse potential applications. In this highlight, we summarize the key progress of ...

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Random mixed-metal Co1-xNix single-chain magnets with simultaneous azide, carboxylate and tetrazolate bridges

03-Jul-2018 | Xiu-Bing Li; Ai-Ling Cheng; En-Qing Gao, Dalton Transactions, 2018

This paper reports the magnetic properties of a series of isomorphous metal-organic frameworks based on random heterometallic Co1-xNix chains with simultaneous azide, carboxylate and tetrazolate bridges. All the mixed-metal compounds show intrachain FM interactions, field-induced metamagnetism, ...

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Energies, Vol. 11, Pages 1696: Efficient Oxidative Desulfurization Processes Using Polyoxomolybdate Based Catalysts

01-Jul-2018 | Granadeiro, Carlos M.; Ferreira, Pedro M. C.; Julião, Diana ; Ribeiro, Luís A.; Valença, Rita ; Ribeiro, Jorge C ..., Energies, 2018

Energies, Vol. 11, Pages 1696: Efficient Oxidative Desulfurization Processes Using Polyoxomolybdate Based Catalysts Energies doi: 10.3390/en11071696 Authors: Carlos M. Granadeiro Pedro M. C. Ferreira Diana Julião Luís A. Ribeiro Rita Valença Jorge C. Ribeiro Isabel S. ...

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Two Lanthanide Metal–Organic Frameworks Constructed by Tris(4-carboxyphenyl)phosphane Oxide with Gas Adsorption and Magnetic Properties

26-Jun-2018 | Tuoping Hu; Qian-Nan Zhao; Liangqin Huo; Lingling Gao; Jie Zhang; xiaoqing wang; Liming Fan, CrystEngComm, 2018

Two lanthanide metal-organic frameworks (LOFs), namely, {[Eu(L3-)(H2O)]•5H2O}n (1), and {[Dy(L3-) (H2O)]•2CH3CN}n (2) have been synthesized based on tris(4-carboxyphenyl)phosphane oxide (H3L) and further characterized by powder X-ray diffraction (PXRD), IR spectra, elemental analyses and ...

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Rational synthesis of luminescent uncommon (3,4,6)-c connected Zn(II) MOF: A dual channel sensor for the detection of nitroaromatics and ferric ion

26-Jun-2018 | Jian-Qiang Liu; Ai-Qing Ma; Jian Wu; Yutong Han; Fuming Chen; Baohong Li; Shaoge Cai; Hui Huang; AMITA SINGH; Abhin ..., Dalton Transactions, 2018

The articulate combination of intriguing functional groups and luminescence property can deliver metal-organic frameworks (MOFs) with multifarious applications viz. selective and specific sensing of nitroaromatic compounds (NACs) an important constituent of explosives as well as sensing of toxic ...

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Two interpenetrated metal-organic frameworks with a slim ethynyl-based ligand: designed for selective gas adsorption and structural tuning

26-Jun-2018 | Xiang-Jing Kong; Yongzheng Zhang; Tao He; Xue-Qian Wu; Ming-Ming Xu; Si-Nan Wang; Lin-Hua Xie; Jian-Rong Jeff Li, CrystEngComm, 2018

In the design and construction of metal-organic frameworks (MOFs), the utilization of slim ligands is usually more inclined to form interpenetrated structures compared with bulky ones. The structural interpenetration can improve the framework stability, and in some cases enhance gas adsorption ...

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A New Water Stable Zinc Metal Organic Framework as an Electrode Material for Hydrazine Sensing

26-Jun-2018 | Manzar Sohail; Muhammad Altaf; Nadeem Baig; Rabia Jamil; Muhammad Sher; Atif Fazal, New Journal of Chemistry, 2018

Metal-organic frameworks (MOFs) are the emerging class of materials representing high surface area, controlled pore size, open metal sites and organic linkers. Utilizing MOFs as direct electrode materials for electrochemical sensing can offer inherent advantages such as containing sensing element ...

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A Two-fold Interpenetrated Zinc-Organic Framework: Luminescent Detection of CrO42-/Cr2O72- and Chemical Conversion of CO2

26-Jun-2018 | Ying Shi; Tian-Qun Song; Chun-Shuai Cao; Bin Zhao, CrystEngComm, 2018

A novel two-fold interpenetrated 3D metal-organic framework {[Zn(DCTP)]∙3.5H2O}n (1) (H2DCTP = 4'-(3,5-dicarboxyphenyl)-4,2':6',4''-terpyridine) was synthesized by pyridine-carboxylic ligand and Zn(OAc)2 under solvothermal conditions. Along the a-axis, a large pore exists in 1 with the size of ...

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