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1,448 Newest Publications about the topic organometallic chemistry

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Philip Power at 65: an icon of organometallic chemistry

01-Jun-2018 | Roland C. Fischer; Michael S. Hill; David J. Liptrot, Dalton Transactions, 2018

We are delighted to present this collection of articles to celebrate the work of Philip Power on the occasion of his 65th birthday. Philip Power at 65: an icon of organometallic chemistry

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Philip Power at 65: an icon of organometallic chemistry

01-Jun-2018 | Roland C. Fischer; Michael S. Hill; David J. Liptrot, Dalton Transactions, 2018

We are delighted to present this collection of articles to celebrate the work of Philip Power on the occasion of his 65th birthday. Philip Power at 65: an icon of organometallic chemistry

more

Dispersion forces play a role in (Me2IPr)Fe([double bond, length as m-dash]NAd)R2 (Ad = adamantyl; R = neoPe, 1-nor) insertions and Fe-R bond dissociation enthalpies (BDEs)

30-May-2018 | Thomas R. Cundari; Brian P. Jacobs; Samantha N. MacMillan; Peter T. Wolczanski, Dalton Transactions, 2018

The effects of dispersion on migratory insertion reactions and related iron–carbon bond dissociation energies pertaining to (Me2IPr)FeR2 (R = neoPe, 1-nor), and the conversion of (Me2IPr)Fe( [[double bond, length as m-dash]] NAd)R2 to (Me2IPr)Fe{N(Ad}R)R are investigated via calculations and ...

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Synthesis, Characterisation and Thermal Properties of Sn(II) Pyrrolide Complexes.

28-May-2018 | Andrew Lee Johnson; James D Parish; Michael William Snook; Gabriele Kociok-Kohn, Dalton Transactions, 2018

SnO is a rare example of a stable p-type semiconductor material. Here, we describe the synthesis and characterisation of a family of Sn(II) pyrrolide complexes for future application in the MOCVD and ALD of SnO thin films. Reaction of the Sn (II) amide complex, [{(Me3Si)2N)}2Sn], with a the ...

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Arrested disproportionation in trivalent, mononuclear, and non-metallocene complexes of Zr(III) and Hf(III)

27-May-2018 | Lauren N. Grant; Matthias E. Miehlich; Karsten Meyer; Daniel J. Mindiola, Chemical Communication, 2018

Reduction of the group 4 transition metal precursors [(PN)2MCl2] (M = Zr (1), and Hf (2)); PN− = (N-(2-(diisopropylphosphino)-4-methylphenyl)-2,4,6-trimethylanilide), both readily prepared by transmetallation of 2 LiPN with [MCl4(THF)2], with a slight excess of KC8, resulted in the isolation of ...

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An isolable [small beta]-diketiminato chlorosilylene

27-May-2018 | Yun Xiong; Shenglai Yao; Arseni Kostenko; Matthias Driess, Dalton Transactions, 2018

The first β-diketiminate ligated chlorosilylene has been synthesised and isolated from the corresponding β-diketiminato dichlorohydrosilane through dehydrochlorination with an N-heterocyclic carbene. Philip Power at 65: an icon of organometallic chemistry

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Phthalocyanine as a redox-active platform for organometallic chemistry

26-May-2018 | Wen Zhou; Daniel B. Leznoff, Chemical Communication, 2018

A systematic approach to the synthesis of σ-organometallophthalocyanines is described. Structurally characterized σ-organoPcM complexes are presented, including the first PcCr–aryl, PcCr–alkynyl, and PcCr–Wittig complexes – representing the first examples of these classes of complexes for any ...

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Mono- and dinuclear tetraphosphabutadiene ferrate anions

26-May-2018 | Uttam Chakraborty; Julia Leitl; Bernd Mühldorf; Michael Bodensteiner; Stefan Pelties; Robert Wolf, Dalton Transactions, 2018

Reduction of [CpArFe(μ-Br)]2 (1, CpAr = C5(C6H4-4-Et)5) by potassium napthalenide, followed by the addition of white phosphorus, affords [K(18-c-6){CpArFe(η4-P4)}] (2, 18-c-6 = [18]crown-6), which features a planar cyclo-P42− ligand. The related diiron complex [Na2(THF)5(CpArFe)2(μ,η4:4-P4)] (3) ...

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Solid-state NMR of quadrupolar nuclei for investigations into supported organometallic catalysts: scope and frontiers

26-May-2018 | D. Grekov; T. Vancompernolle; M. Taoufik; L. Delevoye; R. M. Gauvin, Chemical Society Reviews, 2018

The rational development of heterogeneous catalysts is a prerequisite for improving current catalytic technologies. One of the most successful approaches to achieve this goal is the grafting of organometallic complexes onto a given support, via surface organometallic chemistry (SOMC). In such ...

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Neutral and anionic zinc compounds supported by a bis(imino)phenyl NCN ligand

25-May-2018 | Minh Tho Nguyen; Bulat Gabidullin; Georgii I. Nikonov, Dalton Transactions, 2018

The new zinc complexes 2,6-(ArN [[double bond, length as m-dash]] CH)2C6H3ZnBu (6) and 2,6-(ArN [[double bond, length as m-dash]] CH)2C6H3ZnCl2Li(THF)3 (7), supported by a bis(imino)phenyl NCN pincer ligand, were prepared (Ar = 2,6-iPr2C6H3). The reaction of complex 7 with LiHBEt3 resulted in a ...

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