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6,950 Newest Publications about the topic salts

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Creating Capsules with Cubanes

03-Jul-2018 | Sotaro Kusumoto; Fumiya Kobayashi; Ryo Ohtani; Yingjie Zhang; J. M. Harrowfield; Yang Kim; Shinya Hayami; Masaaki N ..., Dalton Transactions, 2018

A sextuply linked capsule incorporating two Ni(II) cubane units is formed when Ni(II) salts are reacted with N-aminoalkyl salicylamidato ligands in a 4:3 ratio in methanol. With a short (propyl) alkyl substituent, additional chloride counter ions are included in the cavity by occupation of one ...

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First-principles calculations of oxidation potentials of electrolytes in lithium–sulfur batteries and their variations with changes in environment

03-Jul-2018 | Jaebeom Han; Perla B. Balbuena, Physical Chemistry Chemical Physics, 2018

Oxidation potentials of electrolyte molecules in Li–sulfur (Li/S) batteries and their variations in various solvent environments are investigated using first-principles calculations in order to understand oxidative decomposition reactions of electrolytes for cathode passivation. Electrolyte ...

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Synthesis, Characterization and Photocatalytic Activity of Mixed-metal Oxides Derived from NiCoFe Ternary Layered Double Hydroxides

03-Jul-2018 | Duo Pan; Shengsong Ge; Junkai Zhao; Qian Shao; Lin Guo; Xincheng Zhang; Jing Lin; Gaofeng Xu; Zhanhu Guo, Dalton Transactions, 2018

Ternary NiCoFe mixed-metal oxides (NCF-MMOs) with different Ni/Co/Fe ratios were successfully synthesized through a hydrotalcite-like precursor route by co-precipitation of appropriate amounts of metal salts from homogeneous solution, followed by calcination at 600 °C. X-ray diffraction (XRD) ...

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2D networks of metallo-capsules and other coordination polymers from a hexapodal ligand

03-Jul-2018 | Flora L. Thorp-Greenwood; Gilberte Therese Berry; Sophia S. Boyadjieva; Samuel Oldknow; Michaele J. Hardie, CrystEngComm, 2018

The hexapodal ligand hexakis(isonicotinoyl)cyclotricatechylene (L1) belonging to the cyclotriveratrylene family of host-molecules has been synthesised and used in the assembly of a series of coordination polymer materials with Re(i), Co(ii), Cu(ii), Ni(ii) and Ag(i) salts. Single crystal ...

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Palladium catalyzed stereocontrolled synthesis of C-aryl glycosides using glycals and arenediazonium salts at room temperature

03-Jul-2018 | Jeyakumar Kandasamy; Adesh Kumar Singh, Organic & Biomolecular Chemistry, 2018

A stereocontrolled synthesis of aryl-C-glycosides was achieved using glycals and aryldiazonium salts in the presence of palladium acetate. A wide range of glycals including D-glucal, D-galactal, L-rhamanal, D-xylal and D-ribal underwent C-arylation at the anomeric carbon in the presence of ...

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A brush with friction

29-Jun-2018 | Caroline Ash; Marc S. Lavine, Science , 2018

Polymers Polyelectrolyte brushes consist of charged polymer chains attached to a common backbone or surface. They provide excellent lubrication between two surfaces for both engineered and physiological materials. The packing of the brushes is sensitive to pH, temperature, or added salts. Yu et ...

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Diazonium Salt Chemistry For The Design Of Nano-Textured Anti-Icing Surfaces

26-Jun-2018 | Sarra Gam; Jean Pinson; Philippe Decorse; Yun Luo; Remy Herbaut; Laurent Royon; Claire Mangeney, Chemical Communication, 2018

Aryl diazonium salts have emerged as a new generation of robust surface modifiers for a wide range of applications. However, their use for creating anti-icing surfaces has never been investigated so far. We fill this gap by modifying nano-textured copper surfaces with aryl diazonium salts, ...

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Aromatic substitutions of arenediazonium salts via metal catalysis, single electron transfer, and weak base mediation

26-Jun-2018 | Denis Koziakov; Guojiao Wu; Axel Jacobi von Wangelin, Organic & Biomolecular Chemistry, 2018

The re-discovery of arenediazonium salts as stable and easily accessible electrophiles for radical aromatic substitutions initiated by single-electron transfer has led to the development of numerous protocols. The diverse set of methods involving metal-mediated, transition metal-catalyzed, ...

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Materials, Vol. 11, Pages 1084: New Insights on the Photodegradation of Caffeine in the Presence of Bio-Based Substances-Magnetic Iron Oxide Hybrid Nanomaterials

26-Jun-2018 | Palma, Davide ; Bianco Prevot, Alessandra ; Brigante, Marcello ; Fabbri, Debora ; Magnacca, Giuliana ; Richard, Clai ..., Materials, 2018

Materials, Vol. 11, Pages 1084: New Insights on the Photodegradation of Caffeine in the Presence of Bio-Based Substances-Magnetic Iron Oxide Hybrid Nanomaterials Materials doi: 10.3390/ma11071084 Authors: Davide Palma Alessandra Bianco Prevot Marcello Brigante Debora ...

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Zinc(II) Complexes with Uncommon Aminal and Hemiaminal Ether Derivative: Synthesis, Structure, Phosphatase Activity and Theoretical Rationalization of Ligand and Complex Formation

26-Jun-2018 | Debasis Das; Suranjana Purkait; Prateeti Chakraborty; Antonio Frontera; Antonio Bauza; Ennio Zangrando, New Journal of Chemistry, 2018

Condensation of N-(2-hydroxyethyl)ethylenediamine and pyridine-2-carbaldehyde in presence of ZnX2 salts (X = ClO4-, Cl-, Br-, I-) generates four complexes, namely [ZnL1Cl](ClO4) (1), [ZnL1Cl][ZnCl3(H2O)].2H2O (2), [ZnL1Br][ZnBr3(H2O)].2H2O (3), and [Zn(L2)3]I2 (4), where L1 and L2 are aminal and ...

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