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531 Newest Publications about the topic silanes

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A facile, catalytic approach for the synthesis of new organofunctional isocyanurate derivatives

03-Jun-2018 | Author(s): Rafał Januszewski, Michał Dutkiewicz, Bogdan Marciniec, Inorganic Chemistry Communications, 2018

Publication date: July 2018 Source:Inorganic Chemistry Communications, Volume 93 Author(s): Rafał Januszewski, Michał Dutkiewicz, Bogdan Marciniec An effective and selective approach for the synthesis of new organofunctional triallyl isocyanurate derivatives, via hydrosilylation ...

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Amido Ca(II) complexes supported by Schiff base ligands for catalytic cross-dehydrogenative coupling of amines with silanes

30-May-2018 | Alexander Trifonov; Natalia Forosenko; Ivan Basalov; Anton Cherkasov; Georgii K Fukin; Elena Shubina, Dalton Transactions, 2018

A series of amido Ca complexes LCa[N(SiMe3)2](THF) (1−4) coordinated by Schiff base ligands L1−4 were synthesized via amine elimination reaction between proligands L1−4H and bisamido complex Ca[N(SiMe3)2]2(THF)2 in good yields. Unlike Ca[N(SiMe3)2]2(THF)2 the reactions of M[N(SiMe3)2]2(THF)2 (M = ...

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Oligothienyl catenated germanes and silanes: synthesis, structure, and properties

25-May-2018 | Kirill V. Zaitsev; Kevin Lam; Oleg Kh. Poleshchuk; Lyudmila G. Kuz'mina; Andrei V. Churakov, Dalton Transactions, 2018

The synthesis of two new groups of oligothienyl catenated silanes and germanes, Me5M2Thn (1a–b), Me5M2ThnM2Me5 (2a–c) (terminal), and ThnM2Me4Thn (3a–d) (internal) (M = Si, Ge; n = 2, 3; Th = 2- or 2,5-thienyl), is reported. The study of their structural parameters as well as of their spectral ...

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Double uranium oxo cations derived from uranyl by borane or silane reduction

24-May-2018 | Bradley E. Cowie; Gary S. Nichol; Jason B. Love; Polly L. Arnold, Chemical Communication, 2018

A new type of double uranium oxo cation [O–U–O–U–O]4+ is prepared by selective oxygen-atom abstraction from macrocyclic uranyl complexes using either boranes or silanes. A significant degree of multiple U [[double bond, length as m-dash]] O bonding is evident throughout the U2O3 core, but either ...

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Synthesis and some coordination chemistry of the PSnP pincer-type stannylene Sn(NCH2PtBu2)2C6H4, attempts to prepare the PSiP analogue, and the effect of the E atom on the molecular structures of E(NCH2PtBu2)2C6H4 (E = C, Si, Ge, Sn)

23-May-2018 | Javier Brugos; Javier A. Cabeza; Pablo García-Álvarez; Enrique Pérez-Carreño; Diego Polo, Dalton Transactions, 2018

The non-donor-stabilized PSnP pincer-type stannylene Sn(NCH2PtBu2)2C6H4 (1) has been prepared by treating SnCl2 with Li2(NCH2PtBu2)2C6H4. All attempts to synthesize the analogous PSiP silylene by reduction of the (previously unknown) silanes SiCl2(NCH2PtBu2)2C6H4 (2), SiHCl(NCH2PtBu2)2C6H4 (3) ...

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Ormosil-ZrO2 hybrid nanocomposites and coatings on aluminium alloy for corrosion resistance; A sol-gel approach

23-May-2018 | Sreekala Venu Smitha; Syamily S S; A. Mohamed Peer; Balagopal N Nair; Hareesh Unnikrishnan Nair Saraswathy, New Journal of Chemistry, 2018

Corrosion resistant coatings are prepared from a hybrid nanocomposite aerogel derived from the tri-functional silanes, methyl trimethoxy silane (MTMS), glycidyloxy propyl trimethoxy silane (GPTMS) and from zirconium isopropoxide (ZIP) precursor which acts as an inorganic nano-dispersion in the ...

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Materials, Vol. 11, Pages 585: Waterborne Superhydrophobic and Superoleophobic Coatings for the Protection of Marble and Sandstone

10-Apr-2018 | Aslanidou, Dimitra ; Karapanagiotis, Ioannis ; Lampakis, Dimitrios, Materials, 2018

Materials, Vol. 11, Pages 585: Waterborne Superhydrophobic and Superoleophobic Coatings for the Protection of Marble and Sandstone Materials doi: 10.3390/ma11040585 Authors: Dimitra Aslanidou Ioannis Karapanagiotis Dimitrios Lampakis Silica nanoparticles were dispersed in an ...

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Catalytic N-Si Coupling as a Vehicle for Silane Dehydrocoupling via [small alpha]-Silylene Elimination

16-Jan-2018 | Karla A Erickson; Michael P Cibuzar; Neil T Mucha; Rory Waterman, Dalton Transactions, 2018

Exploration of (N3N)ZrNMe2 (1, N3N = N(CH2CH2NSiMe3)33–) as a catalyst for the cross-dehydrocoupling or heterodehydrocoupling of silanes and amines suggests silylene reactivity. Further study of the catalysis and stoichiometric modeling reactions point to α-silylene elimination as the pivotal ...

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Catalytic N-Si Coupling as a Vehicle for Silane Dehydrocoupling via [small alpha]-Silylene Elimination

16-Jan-2018 | Karla A Erickson; Michael P Cibuzar; Neil T Mucha; Rory Waterman, Dalton Transactions, 2018

Exploration of (N3N)ZrNMe2 (1, N3N = N(CH2CH2NSiMe3)33–) as a catalyst for the cross-dehydrocoupling or heterodehydrocoupling of silanes and amines suggests silylene reactivity. Further study of the catalysis and stoichiometric modeling reactions point to α-silylene elimination as the pivotal ...

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Selective Catalytic Synthesis of Amino-Silanes at Part-per Million Catalyst Loadings

30-Dec-2017 | Pablo Ríos; Marta Roselló-Merino; Orestes Rivada-Wheelaghan; Javier Borge; JOAQUIN LOPEZ-SERRANO; Salvador ..., Chemical Communication, 2017

Platinum(II) complex [Pt(ItBu’)(ItBu)][BArF4] (1a) is a highly active and selective catalyst in the dehydrocoupling of amines and silanes at part-per-million catalyst loadings (up to 10 ppm, 0.001 mol%), achieving the highest TON and TOF numbers reported in the literature (up to 1 mmol scale). ...

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