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6 Newest Publications about the topic styrenics


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Inverse vulcanization of elemental sulfur and styrene for polymeric cathodes in Li‐S batteries

16-Sep-2016 | Yueyan Zhang, Jared J. Griebel, Philip T. Dirlam, Ngoc A. Nguyen, Richard S. Glass, Michael E. Mackay, Kookheon Char ..., Journal of Polymer Science Part A: Polymer Chemistry, 2016

ABSTRACT High sulfur content copolymers were prepared via the inverse vulcanization of elemental sulfur with styrene. This reaction was carried out at a relatively low temperature and invokes a new chain transfer mechanism of abstraction of benzylic protons to form stable copolymers. The use ...


A Versatile and Scalable Strategy to Discrete Oligomers

06-May-2016 | Jimmy Lawrence; Sang-Ho Lee; Allison Abdilla; Mitchell D. Nothling; Jing M. Ren; Abigail S. Knight; Carolin Fleischm ..., Journal of the American Chemical Society, 2016

A versatile strategy is reported for the multigram synthesis of discrete oligomers from commercially available monomer families, e.g., acrylates, styrenics, and siloxanes. Central to this strategy is the identification of reproducible procedures for the separation of oligomer mixtures using ...


Simple and Accurate Determination of Reactivity Ratios Using a Nonterminal Model of Chain Copolymerization

24-Sep-2015 | Bryan S. Beckingham; Gabriel E. Sanoja; Nathaniel A. Lynd, Macromolecules, 2015

We propose a new method for the determination of reactivity ratios based on a nonterminal model of copolymerization kinetics. Within the context of this model, we derive simple, reactivity-ratio-dependent expressions whose solution relies solely on monomer consumption information spanning the ...


Strategies for the Synthesis of Thermoplastic Polymer Nanocomposite Materials with High Inorganic Filling Fraction

01-Jul-2013 | Satyajeet Ojha; Alei Dang; Chin Ming Hui; Clare Mahoney; Krzysztof Matyjaszewski; Michael R. Bockstaller, Langmuir, 2013

The governing parameters controlling the miscibility of particle additives within polymeric host media are analyzed for the particular case of silica particle fillers embedded within a poly(methyl methacrylate) (PMMA) matrix. For athermal polymer-graft modification of particles (corresponding to ...


Preparation and characterization of hybrid membranes for fuel cell applications: hydrogenated styrene–butadiene rubber filled with alkyl, phenyl or tolyl sulfonated silica

01-Mar-2011 | Pilar G Escribano; Maria J Cánovas; Maria C Ojeda; Carmen del Río; Félix Sánchez; Jose L Acosta; Pilar Garcia Escribiano, Polymer International, 2011

Abstract Polymers with ionic groups attached (ionomers) are indispensable electrolyte materials for proton exchange membrane fuel cells. Nafion®, a widely used membrane, has many disadvantages: price, high methanol crossover and conductivity loss at temperatures above 80 °C. This work reports ...


High Tg microspheres by dispersion copolymerization of N‐phenylmaleimide with styrenic or alkyl vinyl ether monomers

01-Jan-2011 | Krishnamoorthy, Swapna; Haria, Mehul; Fortier‐mcgill, Blythe E.; Jafar Mazumder, M. A.; Robinson, Erica I.; X ..., Journal of Polymer Science Part A: Polymer Chemistry, 2011

Abstract Solution and dispersion copolymerizations of N‐phenylmaleimide (PMI) with either styrenics or alkyl vinyl ethers (AVEs), systems with a tendency to give alternating polymers, were investigated with the goal of producing high glass transition particles. Equimolar solution ...


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