Azirines

Azirines are three membered heterocyclic unsaturated (i.e. they contain a double bond) compounds containing a nitrogen atom and related to the saturated analogue aziridine ^[1]. They are highly reactive yet are found in a number of natural products such as the antibiotic azirinomycin, isolated from Streptomyces auras.

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The strained ring system undergoes reactions that favor ring opening and can act as a nucleophile or an electrophile.

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