To use all functions of this page, please activate cookies in your browser.
With an accout for my.chemeurope.com you can always see everything at a glance – and you can configure your own website and individual newsletter.
- My watch list
- My saved searches
- My saved topics
- My newsletter
Additional recommended knowledge
The coordination sphere of the metal ligands sterically restricts the entry of olefins - this being enhanced by the use of internal donors (succinates, phthalates etc) & external donors (substituted silanes) (ref: www.answers.com/topic/coordination-polymerization)
Polymerization is thought to start with coordination of the olefin to the the vacant site of an activated Ti-R species and subsequent insertion into the Ti-R bond (ref: dissertations.ub.rug)
|This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Cossee-Arlman_mechanism". A list of authors is available in Wikipedia.|