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Electride



  An electride is an ionic compound in which an electron is the anion.[1] The first electrides to be studied in depth were solutions of alkali metals in ammonia.[2] When sodium metal dissolves in ammonia, the result is a blue solution consisting of [Na(NH3)6]+ and solvated electrons. Such solutions are powerfully reducing, as demonstrated by their use in Birch Reductions. Evaporation of these blue solutions affords a mirror of Na. Such solutions slowly lose their colour as the electrons reduce ammonia:

[Na(NH3)6]+e- + NH3NaNH2 + H2

Additional recommended knowledge

Addition of 2,2,2-cryptand to a solution of [Na(NH3)6]+e- affords [Na(2,2,2-crypt)]+e-. Evaporation of these solutions yields a blue-black paramagnetic salt with the formula [Na(2,2,2-crypt)]+e-. Such salts decompose above 240 K. In these salts, the electron is delocalized between the cations. Electrides are paramagnetic and Mott insulators.

References

  1. ^ Dye, J. L. "Electrons as Anions" Science 2003, Volume 301, pp. 607 - 608. DOI: 10.1126/science.1088103
  2. ^ Holleman, A. F.; Wiberg, E. "Inorganic Chemistry" Academic Press: San Diego, 2001. ISBN 0-12-352651-5.

J. L. Dye, M. J. Wagner, G. Overney, R. H. Huang, T. F. Nagy, and D. Tománek. Cavities and Channels in Electrides. J. Am. Chem. Soc. 118, 7329 (1996).

 
This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Electride". A list of authors is available in Wikipedia.
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