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In chemistry, a formal charge (FC) is a partial charge on an atom in a molecule assigned by assuming that electrons in a chemical bond are shared equally between atoms, regardless of relative electronegativity  or in another definition the charge remaining on an atom when all ligands are removed homolytically .
The formal charge can be calculated by the following equation: FC = number of valence electrons of the atom - number of lone pair electrons on this atom - half the total number of electrons participating in covalent bonds with this atom.
Additional recommended knowledge
An alternative method for assigning charge to an atom taking into account electronegativity is by oxidation number. Other related concepts are valence which counts number of electrons that an atom uses in bonding and coordination number, the number of atoms bonded to the atom of interest.
Ammonium NH4+ is a cationic species. By using the vertical groups of the atoms on the periodic table it is possible to determine that each hydrogen contributes 1 electron, the nitrogen contributes 5 electrons, and the charge of +1 means that 1 electron is absent. The final total is 8 total electrons (1 × 4 + 5 − 1). Drawing the Lewis structure gives an sp3 (4 bonds) hybridized nitrogen atom surrounded by hydrogen. There are no lone pairs of electrons left. Thus, using the definition of formal charge, hydrogen has a formal charge of zero (1-(0 + ½ × 2)) and nitrogen has a formal charge of +1 (5−(0 + ½ × 8)). After adding up all the formal charges throughout the molecule the result is a total formal charge of +1, consistent with the charge of the molecule given in the first place.
Note: The total formal charge in a molecule should be as close to zero as possible, with as few charges on the molecule as possible
Even though all three structures gave us a total charge of zero, the final structure is the superior one because there are no charges in the molecule at all
Although the formula given above is correct, it is often unwieldy and inefficient to use. A much quicker and still accurate method is to do the following:
Again, this method is just as accurate as the one cited above, but is much easier to use. It is important to keep in mind that formal charges are just that-formal, in the sense that this system is a formalism. Atoms in molecules do not have "signs around their necks" indicating their charge. The formal charge system is just a method to keep track of all of the valence electrons that each atom brings with it when the molecule is formed.
|This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Formal_charge". A list of authors is available in Wikipedia.